An introductory guide to deducing the mechanism of chemical reactions is presented. Following a typical workflow for probing reaction mechanism, the guide introduces a wide range of kinetic and mechanistic tools. In addition to serving as a broad introduction to mechanistic analysis for students and researchers, the guide has also been used by…

The problem of obtaining the apparent equation of motion and shape of a moving body from its arbitrary given equation of motion in special relativity is considered. Also the inverse problem of obtaining the body's equation of motion from a known equation of motion of its image is discussed. Some examples of this problem solution are considered. As…

Proposes a simple procedure based on an expansion of the exponential terms of Raoult's law by applying it to the case of the benzene-toluene mixture. The results with experimental values are presented as a table. (YP)

Outlines a laboratory exercise that makes use of Beer's Law plots of cysteine constructed at several pH values over a broad range of wavelengths to estimate the tautomeric ratio (R) of two singly charged ionic forms, calculate the microscopic constants, and construct ultraviolet spectra for both light absorbing species. (CW)

Determined student opinion of the investigative laboratory by surveying both students who had completed an introductory biology course using this format and another group of more advanced students who had taken other courses since this one. Results show that a majority of students feel the format improved their problem-solving skills. (JN)

Examines the psychology of learning and its application to work in the laboratory. States that the working memory capacity of students is limited; therefore the amount of information they can process needs to be controlled and "recipe following" in the laboratory is perfectly reasonable. (RT)

Examines the usefulness of cyclic voltammetry to the determination of a complex compound's stoichiometry. Discusses the experimental design, laboratory equipment, and results. (CW)

Criticizes the way organic chemistry teaching laboratory experiments are approached from the viewpoint of physical chemistry. Compares these experiments to cooking. Stresses that what matters is not the practice of the finger skills of organic chemistry but practice in the style of thinking of organic chemists. (CW)

Describes an experiment for undergraduate chemistry laboratories involving a chemical found in plants and some sea animals. Discusses collection and identification of material, a hemolysis test, preparation of blood-coated agar plates, and application of samples. (CW)

Describes a demonstration procedure using controlled reduction potentials to predict observed color changes which are then experimentally verified. Demonstrates the usefulness of this procedure in helping students understand LeChatelier's principle and the solubilit rule "like dissolves like." (CW)

Discusses the theory and history behind an experiment that will be performed to measure the gravitational forces that effect antimatter. Describes conditions under which the principle of equivalence would be violated or supported. Reviews historical tests of equivalence, current theory and experiments. Presents the design of the new experiment.…

Describes experiments in which students prepare in situ soluble complexes of metal ions with different ligands and observe and estimate the change in formal potential that the ion undergoes upon complexation. Discusses student formation and analysis of soluble complexes of two different metal ions with the same ligand. (CW)

Describes a laboratory exercise in which acid dissociation constants and molecular weights are extracted from sample data and the sample is identified. Emphasizes accurate volumetric work while bringing to practice the concepts of acid-base equilibria, activity coefficients, and thermodynamic constants. (CW)

Describes an application of potentiometry to the determination of acidic and basic compounds in household cleaners in chemistry instruction. Discusses procedures and results of this experiment. (CW)

Described is a study which was developed to find the proportion of cross-dominance in young adults. Procedures and statistical tests are discussed. The tasks used in the assessment of cross-dominance are described. Results indicated that all persons suffered from some cross-dominance. (CW)