Although diffusion is the subject of beginning chemistry classes, there are a variety of experiments, such as the spread of perfume in the classroom, that are often "incorrectly" explained by diffusion alone. To eliminate this common misconception, a recently published method is modified to determine the diffusion constant of hydrogen…

The family resemblance approach to nature of science is receiving increasing attention by science educators since its inception about a decade ago. Many scholars of science education have contributed and continue to contribute to it not only theoretically but also by applying it empirically to a wide range of areas such as curriculum and textbook…

In this two-session experiment for an organic chemistry lab, students prepare a macrocyclic host compound--namely, a pillar[5]arene--by means of a templated 1,4-dimethoxybenzene/formaldehyde cyclo-oligomerization (session 1), and then, they explore its molecular recognition properties toward the 1,8-diaminooctane guest with the aid of [superscript…

The variation in the transference number of H[superscript +] (aq) is investigated for different HCl solution concentrations. The method for scribing graduations on electromigration tubes is modified to decrease the error in experimental measurements, and metallic copper is used as the anode to reduce the toxicity and environmental impact of the…

Historical scientific controversies have great potential to address aspects of the nature of science in context. This paper describes a design case about a novel lesson plan based on the scientific controversy between Karl von Frisch and Carl von Hess on the sight of bees (how they see). This lesson plan allows concepts related to experimentation,…

A laboratory experiment that involves the aqueous and solid phase synthesis, characterization, and solvatochromic properties exploration of red complex [Ni(Me[subscript 3]en)(acac)]BPh[subscript 4] has been developed for first-year undergraduates in the College of Chemistry and Chemical Engineering at Xiamen University. In contrast to previously…

The addition of a small excess of triethyl orthoformate to an alcoholic mixture of NiCl[subscript 2]·6H[subscript 2]O and triphenylphosphine (PPh[subscript 3]) results in an increase in the typical isolated yield of [NiCl[subscript 2](PPh[subscript 3])[subscript 2]] from below 50% to over 85%. The impact of water when present in the reaction…

Students determine the iron mass in dietary supplements using four colorimetric assays. These colorimetric assays were selective for Fe[superscript 3+]. It was complexed by thiocyanide, salicylate, gallic acid, and Fe(CN)[subscript 6][superscript 4-], forming blood-red, red, violet, and blue complexes, respectively. The [lambda][subscript max] of…

Benzoin, an [alpha]-hydroxy ketone, is stereoselectively reduced by sodium borohydride to yield hydrobenzoin, the stereochemistry of which is determined by acetalization and analysis of the derivative by NMR spectroscopy. This classical experiment has been enhanced by modern spectroscopic and computational analysis to enable students to…

Lakes are artists' pigments made from colorants bound to an inert substrate, usually hydrated aluminum oxide. Before the late 19th century, lakes were made from natural pigments extracted from plants and insects, extracted either directly from the dyestuff or indirectly from waste materials generated in the manufacture of dyed textiles. The first…

Most students enter college without any exposure to polymer science, which leads to the poor understanding and slow implementation of plastic recycling programs in the United States. To address the knowledge gap in chemical recycling, we introduce a 2-part laboratory experiment that was conducted in multiple high schools and public outreach events…

In this article, we discuss the replication of a forgotten chemical instrument in the context of undergraduate chemistry education. Together with students, we have attempted to replicate an eighteenth century "eudiometrical" procedure. Eudiometry was the practice of measuring the "goodness" of the air by looking at the volume…

An undergraduate laboratory experiment has been developed for the synthesis of a reactive cross-linker that is useful in various highly visual demonstrations of organic reactivity, click chemistry, and biobased polymer synthesis. A triazolinedione-based cross-linker, which is known as a useful reagent for click chemistry, can be obtained from…

The chemical experiment in this study is specifically created for undergraduate students studying energy and the environment. The target of the experiment is for students to comprehend the deactivation mechanism of the Ce/TiO[subscript 2] catalyst by oxides of phosphorus through practical experiments and enhance their knowledge of environmental…

We describe a three-day advanced organic laboratory experience that includes the solid-phase synthesis of an unknown three amino acid polypeptide for junior/senior undergraduate chemistry majors. Students conduct a series of 1D and 2D NMR experiments (HSQC, HMBC, TOCSY) and analyze the data to identify the side chain residues of the peptide and…