Plant extracts and their components have been reported to have antimicrobial properties against phytopathogens. Although such properties could be harnessed for the development of new pathogen control strategies, there are no standardised methods for their assessment in different extracts. The laboratory exercise presented here involves the use of…

Owing to the critical role of stereochemistry in biotechnology, medicine, and industry, it must be well represented in undergraduate lab curricula. To achieve these stereochemical laboratory requirements without sacrificing existing lab techniques, we modified two standard laboratory experiments to include chiral GC analysis as follows. (1) The…

Stereoselective reduction of ketones to alcohols using baker's yeast is a classic experiment in the undergraduate laboratory. Here we illustrate the reduction of racemic ethyl 2-fluoro-3-oxobutanoate to the corresponding alcohol using a set of four commercially available ketoreductases (KREDs). The reaction sets two stereocenters with four…

Metal-organic frameworks (MOFs) are porous materials composed of metal ions and organic ligands. These materials have garnered significant attention due to their wide-ranging applications, such as the capture of hazardous molecules, catalysis, production of value-added compounds, and detection of ions or molecules in water. Despite their immense…

The variation in the transference number of H[superscript +] (aq) is investigated for different HCl solution concentrations. The method for scribing graduations on electromigration tubes is modified to decrease the error in experimental measurements, and metallic copper is used as the anode to reduce the toxicity and environmental impact of the…

A multicomponent reaction was adapted and successfully applied in the major organic course, which involves synthesizing and characterizing a 1,3-benzoxazine derived from paracetamol extracted from tablets of the worldwide well-known medicine Tylenol. Using paracetamol as a reagent is a motivational strategy in undergraduate laboratories to meet…

A laboratory experiment that involves the aqueous and solid phase synthesis, characterization, and solvatochromic properties exploration of red complex [Ni(Me[subscript 3]en)(acac)]BPh[subscript 4] has been developed for first-year undergraduates in the College of Chemistry and Chemical Engineering at Xiamen University. In contrast to previously…

A new undergraduate thin-layer chromatography laboratory experiment devoted to quantitative determination of disulfiram in Anticol formulation is presented. The proposed activity can be a part of a chromatographic methods of analysis course as well as a general chemistry course. To carry out a quantitative analysis, an image analysis technique was…

The substitution of carbonyl compounds with liquid bromine as a brominating agent is the most commonly employed synthesis method for a-bromoacetophenone and its derivatives. However, liquid bromine possesses certain drawbacks, such as volatilization, high toxicity, strong corrosion, and poor reaction selectivity, which limit its application and…

Here, a relatively simple laboratory experiment of a physical pendulum, suitable for students of science and engineering in the first courses of university physics, is presented to illustrate its dynamic behavior and to determine its inertia moment. To this end, a long wooden rod of length L = 99.8 cm and cross-section radius R = 1.73 cm was used…

While elimination reactions are ubiquitous in organic chemistry textbooks, their implementation in undergraduate laboratories still suffers from a lack of reliable and easy setup procedures. This paper describes an easy-to-implement set of elimination experiments in the pentanol and bromopentane series using a modified Hickman distillation head.…

In this laboratory experiment, a guided inquiry exploring the physicochemical principles of the dissolution of Ca(OH)[subscript 2](s) in water is proposed for laboratory classes in university and high school. As part of students' inquiry, two experimental approaches are used. One is the change in solubility with temperature revealed by measuring…

Electrophilic aromatic substitution reactions are common in the organic chemistry laboratory. These reactions, while ubiquitous, use corrosive reagents and halogenated or hydrophobic solvents that produce expensive and hazardous waste streams. The carboxylation of phenols (Kolbe-Schmitt reaction), although aqueous, typically involves conditions…

A solenoid is a coil wound many times on a cylinder of length greater than its diameter. Solenoids are mainly used as electromagnets, because a magnetic field is formed when current flows through a solenoid. The solenoid described in secondary school and university textbooks is a single-layered solenoid. Further, textbooks and papers focusing on…

Removing the pollutants from various wastewater is crucial to the environment, ecology, and humans. However, the pollutants are generally removed by chemical decomposition, which not only consumes a lot of energy but also produces carbon emissions. Electrochemical flocculation is effective to extract pollutant molecules and heavy ions from…