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Jameson, Greg; Brüschweiler, Rafael – Journal of Chemical Education, 2020
The Boltzmann distribution lies at the heart of essentially all of statistical thermodynamics. In most textbooks, this distribution is introduced either "ad hoc" or it is mathematically derived by constrained entropy optimization using the method of Lagrange multipliers. Unfortunately, when students enroll in a statistical thermodynamics…
Descriptors: Computer Simulation, Science Instruction, Thermodynamics, Statistics
Gardenier, George H.; Gui, Feng; Demas, James N. – Journal of Chemical Education, 2011
Complex error propagation is reduced to formula and data entry into a Mathcad worksheet or an Excel spreadsheet. The Mathcad routine uses both symbolic calculus analysis and Monte Carlo methods to propagate errors in a formula of up to four variables. Graphical output is used to clarify the contributions to the final error of each of the…
Descriptors: Monte Carlo Methods, Computer Software, Calculus, Mathematics Education