An introductory guide to deducing the mechanism of chemical reactions is presented. Following a typical workflow for probing reaction mechanism, the guide introduces a wide range of kinetic and mechanistic tools. In addition to serving as a broad introduction to mechanistic analysis for students and researchers, the guide has also been used by…

Recent science reform documents have called for incorporating authentic scientific discourse into science classes as engaging in discourse has shown to result in numerous benefits. Whether these benefits are observed in students depends upon the quality of the discourse in which they engage. However, characterizing the quality of student-student…

The National Science Foundation funded a synthesis study on the status, contributions, and future direction of discipline-based education research (DBER) in physics, biological sciences, geosciences, and chemistry. DBER combines knowledge of teaching and learning with deep knowledge of discipline-specific science content. It describes the…

This study described the process of developing and validating the College Chemistry Self-Efficacy Scale (CCSS) that can be used to assess college students' beliefs in their ability to perform essential tasks in chemistry. In the first phase, data collected from 363 college students provided evidence for the validity and reliability of the new…

Despite several decades of research into the teaching and learning of Science/Chemistry, at both secondary and tertiary level, it has had relatively little impact on practice. In many countries interest in studying Science at school and university is falling, and there is concern over falling numbers and falling standards. There is a changing…

Presented are three theories of superconductivity: (1) the London theory; (2) the Bardeen, Cooper, Schrieffer (BCS) theory; and (3) the sudden-polarization theory. (RH)

This is Part II in a series on Fourier transforms. Described are Fourier transform techniques using spectrometers in chemistry. Advantages of the technique are discussed. (RH)

This is Part II in a series on Fourier transform infrared spectroscopy (FT-IR). Described are various advantages of FT-IR spectroscopy including energy advantages, wavenumber accuracy, constant resolution, polarization effects, and stepping at grating changes. (RH)

This review of standard atomic weights is written chiefly for chemical analysts who may place too much confidence in the accuracy of these values. Topics considered include Frank Clarke's atomic weights, effects of radioactivity and other anomalies in isotopic abundance, atomic weight limitations from experimental uncertainties, and others. (JN)

Reviews techniques for online coupling of high-performance liquid chromatography with mass spectrometry, emphasizing those suitable for application to nonvolatile samples. Also summarizes the present status, strengths, and weaknesses of various techniques and discusses potential applications of recently developed techniques for combined liquid…

A Prelaboratory Preparation Period (PPL) was developed to introduce freshmen level students to weekly laboratories. Results (based on data obtained from 233 chemistry students) show that the PPL increased the academic achievement of students enrolled in the introductory chemistry course. (JN)

Employs latent partition analysis (a multivariate technique) to reveal pre/postcognitive structure of freshman engineering students (N=70) taking general chemistry. Similarities and dissimilarities among high and low scorers are discussed. Arguments for use of this statistical techniques are presented. (DH)

Examines recent developments in techniques for obtaining high-resolution nuclear magnetic resonance (NMR) spectra on solid samples, discussing the kinds of applications for which these techniques are well suited. Also discusses the characteristics of NMR of solids and generating magnetization for NMR in solids. (JN)

Focuses on a recent approach to chirality that seeks to call attention to the fact that current usage of this term is often inconsistent with its proper relationship to molecular structure. (TW)

This paper explores how Fourier Transform (FT) mimics spectral transformation, how this property can be exploited to advantage in spectroscopy, and how the FT can be used in data treatment. A table displays a number of important FT serial/spectral pairs related by Fourier Transformations. A bibliography and listing of computer software related to…