This laboratory experiment consists of the synthesis of two series of alkaline-earth titanates (calcium-strontium and strontium-barium)to corroborate Vegard's law by obtaining their X-ray diffraction patterns and plotting the lattice parameter versus mole fraction of both cations. This experiment allows students to understand the key concepts in…

Ultrafast laser pump-probe spectroscopy is an important and growing field of physical chemistry that allows the measurement of chemical dynamics on their natural time scales, but undergraduate laboratory courses lack examples of such spectroscopy and the interpretation of the dynamics that occur. Here we develop and implement an ultrafast…

The Beer-Lambert law is a fundamental relationship in chemistry that helps connect macroscopic experimental observations (i.e., the amount of light exiting a solution sample) to a symbolic model composed of system-level parameters (e.g., concentration values). Despite the wide use of the Beer-Lambert law in the undergraduate chemistry curriculum…

Affect and emotions matter to science learning. They also matter because they are integral to science identity formation and sense of belonging. This study aims to foreground the epistemic and affective character of laboratory work in higher science education by conceptualizing it as epistemic practice, in which students activate their body and…

Electrophoresis is integral to analytical and biochemistry experiences in undergraduate education; however, fundamental principles of the method are often taught in upper-level laboratories through hands-on experiences. A laboratory activity is reported that teaches the concepts of electrophoretic mobility and electroosmotic flow. A single…

A new experiment based on phase inversion of Pickering emulsions was carried out in a physical chemistry course. The emulsions were stabilized by surfactant-modified SiO[subscript 2] particles. As the concentration of surfactant increased, the emulsions changed from oil-in-water type (O/W) to water-in-oil type (W/O) type, and then reverted to be…

A versatile experiment is described for the high school and college laboratory setting based on the synthesis of biobased polymers prepared from inexpensive, renewable, and nonhazardous chemicals. Combinations of readily available citric acid, glycerol, and tapioca root starch are used to prepare three polymeric materials with different observable…

This study focused on exploring and evaluating students' views of the Nature of Science in the context of undergraduate chemistry laboratory. Thirty-six undergraduate students doing a laboratory course in upper division physical chemistry were assessed using an open-ended instrument and assessment criteria that categorise them in three levels of…

A problem-based learning (PBL) methodology was implemented to a project, whose main objectives were to discuss and apply the Twelve Principles of Green Chemistry to the study of poly(vinyl alcohol)'s cross-linking reaction with dicarboxylic acids. The five participating students were oriented to be responsible for their own learning and the…

This article seeks to provide researchers and practitioners in laboratory education, particularly those involved in the curriculum design and implementation of teaching laboratories at university level, with a conceptual framework and a working model for an integrated assessment of learning domains, by attending to a more holistic approach to…

As described by the National Research Council, science practices reflect, in part, the way science is done. When researchers are developing an explanation for a phenomenon, they are using a combination of knowledge and skills reflected in the science practices. Laboratory-based chemistry courses provide the opportunity for students to move beyond…

A guided inquiry-based experiment exploring the regioselectivity of the hydration of phenylacetylene is described. The experiment uses an acidic gold(III) catalyst in a benign methanol/water solvent system to introduce students to alkyne chemistry and key principles of green chemistry. The experiment can be easily completed in approximately 2 h,…

Electrochemistry is primarily taught in first-year undergraduate courses through batteries; this lab focuses instead on corrosion to apply electrochemical concepts of electrolytes, standard reduction potentials, galvanic cells, and other chemistry concepts including Le Chatelier's Principle and Henry's Law. Students investigate galvanic corrosion…

This paper reports an undergraduate laboratory experiment to measure heterogeneous liquid/gas reaction kinetics (ozone-oleic acid and ozone-phenothrin) using a flow reactor coupled to an attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectrometer. The experiment is specially designed for an upper-level undergraduate Physical…

The enthalpy of vaporization (?H[subscript vap]) of salt solutions is not easily measured, as a certain quantity of pure water has to be evaporated from a solution, at constant composition, and at a fixed temperature and pressure; then the corresponding heat input has to be measured. However, a simple bubble column evaporator (BCE) was used as a…