Commonly used methods to simulate the oxidation-reduction (redox) titration curves include the three-step method and the rigorous method. The simple three-step method simulates the redox titration curve with the assumption that the reaction is complete, which is widely used in undergraduate quantitative analysis courses. For the rigorous…

The methodology and mathematical treatment of several classic multivariate methods for the analysis of spectroscopic data is demonstrated in a straightforward way that can be used as a basis for teaching an undergraduate introductory course on chemometric analysis. The multivariate techniques of classical least-squares (CLS), principal component…

Shows that the rules of thumb for propagating significant figures through arithmetic calculations frequently yield misleading results. Also describes two procedures for performing this propagation more reliably than the rules of thumb. However, both require considerably more calculational effort than do the rules. (JN)

Presents compact algorithms, suitable for use with hand held calculators, for the calculation of potentiometric titration curves. (SL)

Presents an exact equation for calculating the volume of titrant as a function of the hydrogen ion concentration suitable for calculation on a hand held calculator. (SL)

Ninety students in an introductory chemistry class were divided into three groups to test the power of algorithms to increase logical thinking abilities. The experimental group received approximately 10 hours of laboratory instruction based on the use of procedural algorithms. Experiment and control groups were tested for logical thinking…

Presents a computational method based on a Monte Carlo generation of a large number of chemical reactions. The reactions are allowed to proceed on the basis of relative probabilities. (MLH)

Describes an algorithm that provides more rapid convergence for more complicated forms of phase separation requiring the use of a digital computer. Demonstrates that this "inside-out" algorithm remains efficient for determination of the equilibrium states for any type of phase transition for a binary system. (CW)

Discusses the differences between problems and exercises in chemistry, and some of the difficulties that arise when the same methods are used to solve both. Proposes that algorithms are excellent models for solving exercises. Argues that algorithms not be used for solving problems. (TW)

Discusses the difference between a generic chemistry problem (one which can be solved using an algorithm) and a harder chemistry problem (one for which there is no algorithm). Encourages teachers to help students recognize these categories of problems so they will be better able to find solutions. (TW)

Discusses the differences between problems and exercises, the levels of thinking required to solve them, and the roles that algorithms can play in helping chemistry students perform these tasks. Proposes that students be taught the logic of algorithms, their characteristics, and how to invent their own algorithms. (TW)

Reports on a study in which two spatial tests were given to science and engineering majors and to students in nursing and agriculture at Purdue University (Indiana). Scores from the tests consistently contributed a small but significant amount of success on measures of performance in chemistry. (TW)

Suggests a method for solving verbal problems in chemistry using a linguistic algorithm that is partly adapted from two artificial intelligence languages. Provides examples of problems solved using the mental concepts of translation, rotation, mirror image symmetry, superpositioning, disjoininng, and conjoining. (TW)

Reports on a study which examined the relationship between spatial ability and performance in organic chemistry. Results indicated that students with high spatial scores did significantly better on questions requiring problem solving skills, as well as on those requiring the mental manipulation of two-dimensional representations of a molecule. (TW)