In this paper, we show a laboratory experience describing the possibility to build a sensor using a coil to measure small thicknesses of materials with the possibility of measuring temperature simultaneously, with the same built sensor. Its operation is based on the following facts: An electric current (a.c), flows through a coil and a magnetic…

The Hofmeister series is a recurring trend that ranks ions' abilities to influence various aqueous processes in solution. Herein, a set of project-based experiments was developed for students in an upper-level physical chemistry laboratory to investigate the specific ion effects on the thermodynamics of caffeine partitioning between aqueous and…

This work describes a simple experiment to measure the resistor temperature as a function of the applied power and proves that it is an efficient way to introduce some important physical concepts in classroom, including the Joule's first law, hot-spot temperature, thermal resistance, thermal dissipation constant, time constant and the Newton's law…

Project-based learning has been shown to be an effective pedagogical strategy that motivates students and thus promotes learning. In this article we describe a project-based unit centered on the physics of solar cookers (Fig. 1 and 3). Our goal was to elevate the solar cooker from a summer camp activity to a college-level project that could be…

Many types of batteries power an ever-growing number of devices. Electrochemical devices like batteries and fuel cells can, in principle, exceed Carnot efficiency for energy conversion. In this novel laboratory experiment, students explore the partitioning of the enthalpy change of a battery's electrochemical reaction between useful electrical…

Quantum dots (QDs) are useful for demonstrating the particle-in-a-box (PIB) model utilized in quantum chemistry, and can readily be applied to a discussion of both thermodynamics and kinetics in an undergraduate laboratory setting. Modifications of existing synthetic procedures were used to create QDs of different sizes and compositions (CdS…

This paper describes an undergraduate laboratory experiment where students study the heating behavior of magnetic nanoparticles in the presence of alternating magnetic fields. Average score on the post-test was 45±12% for students who completed the lab online, versus 43±11% for those doing the activity hands-on. Post-test scores were significantly…

As the need for alternative energy becomes increasingly important, energy research and related industries are rapidly expanding. This lab incorporates current energy-storage research into a second-year lab that instills real-world, industry-relevant knowledge and skills while teaching and reinforcing physical-chemistry concepts. A manganese oxide…

Piezoelectric and pyroelectric materials are used in many current applications. The purpose of this paper is to explain the basic properties of pyroelectric and piezoelectric effects and demonstrate them in simple experiments. Pyroelectricity is presented on lead zirconium titanate (PZT) ceramics as an electric charge generated by the temperature…

In this paper, we present a low-cost method to study the Gay-Lussac's law. We use a heating wire wrapped around the test tube to heat the air inside and make use of a solid state pressure sensor which requires a previous calibration to measure the pressure in the test tube.

The refrigeration process reduces the temperature of a space or a given volume while the power generation process employs a source of thermal energy to generate electrical power. Because of the importance of these two processes, training of engineers in this area is of great interest. In engineering courses it is normally studied the vapor…

The objective of this paper is to present a laboratory program designed for the Thermodynamics course offered in the Department of Thermal Engineering at the University of the Basque Country. With reference to one of the examples given in the textbook by Moran, Shapiro, Boettner and Bailey (2012), the balances of mass, energy, entropy and exergy…

In this article we examine cases of more classical and less classical nature compared to results found by quantum mechanics and attribute a form of Free Energy discontinuity for each case within a boundary layer. The concept of a boundary layer is broadened as to include areas of first or second variations of the Gibbs free energy. It is…

An experiment is described that determines the activation energy (E[subscript a]) of the iodide-catalyzed decomposition reaction of hydrogen peroxide in a much more efficient manner than previously reported in the literature. Hydrogen peroxide, spontaneously or with a catalyst, decomposes to oxygen and water. Because the decomposition reaction is…

A simple, affordable hydrogen proton exchange membrane (PEM) fuel cell laboratory was developed through a collaborative effort between faculty and undergraduate students at Brown University. It has been incorporated into the introductory chemistry curriculum and successfully implemented in a class of over 500 students per academic year for over 3…