The concepts of electronegativity and classical electronegativity scales are briefly described. Electronegativity scales have practical quantitative applications, and this work suggests activities which can assist students select the scales for use in chemistry applications. It provided examples of the use of an appropriate electronegativity…

Eigentheory concepts are central in mathematics and physics; they serve multiple functions, such as symbolizing physical phenomena and facilitating mathematical computations. Words and meanings associated with eigentheory develop and vary over time, as do their associated symbols. In this study, we investigate how "eigen" develops over…

VibHam is an adaptable and user-friendly program designed for advanced diatomic molecule spectroscopy beyond the harmonic oscillator approximation. It employs numerical solutions to the rovibrational Schrödinger equation, accurately reproducing spectroscopic constants and offering insights into rovibrational wave functions, energy levels, and…

In the present work, we demonstrate the phenomenon of temperature difference power generation, which is achieved by the reversible conversion between thermal and electrical energy.

Keto-enol tautomerization is paramount to understanding the mechanisms involved in many organic reactions and biochemical transformations. Isomerization of an enol to a carbonyl compound is typically introduced during the discussion of the acid-catalyzed electrophilic addition of water to alkynes. The tautomerization of carbonyl compounds to enol…

Common wisdom holds that ATP hydrolysis is spontaneous because of the weakness of its phosphoanhydride bonds, electrostatic repulsion within the polyanionic ATP[superscript 4]-molecule, and resonance stabilization of the inorganic phosphate and ADP products. By examining the pH-dependence of the hydrolysis Gibbs free energy, we show that in fact,…

Engineering design that requires mathematical analysis, scientific understanding, and technology is critical for preparing students for solving engineering problems. In simulated design environments, students are expected to learn about science and engineering through their design. However, there is a lack of understanding concerning linking…

As a widely applied theory that has found success across many fields, density functional theory (DFT) is largely taught. Typically, the most effective way to convey DFT concepts is through illustrative examples that are currently lacking in available resources. In this work, we demonstrate total energy calculations for H[subscript 2] using…

The conceptual gambit of this article is to propose that the notion of anti-entropy should be complemented by that of exergy investment or destruction, a term first proposed by Zoran Rant in 1956. It argues that one of Bernard Stiegler's most important interventions into deconstruction is the thermodynamic reformulation of Derridean…

Ion transport, involving the diffusion and migration of ions within the electrolyte, stands as a fundamental concept in electrochemistry and serves as the driving force for electrochemical reactions. Electric double layers are critical in the fields of electrochemical energy storage and chemical conversion, constituting a central focus of…

Previous research has shown that students employ intuitive thinking when understanding scientific concepts. Three types of intuitive thinking--essentialist, teleological, and anthropic thinking--are used in biology learning and can lead to misconceptions. However, it is unknown how commonly these types of intuitive thinking, or cognitive…

Although researchers have extensively studied student conceptions of radioactivity, the conceptions held by preservice teachers on this subject are largely absent from the literature. We conducted a qualitative content analysis of problem-centered interviews with preservice teachers (N=13) to establish which conceptions are held by preservice…

The Brief Electricity and Magnetism Assessment (BEMA) is a multiple-choice instrument commonly used to measure introductory undergraduate students' conceptual understanding of electricity and magnetism. This study used a network analysis technique called modified module analysis-partial (MMA-P) to identify clusters of correlated responses, also…

A novel teaching approach is aimed at elucidating the concept of bond enthalpy for general chemistry students. Through the integration of a hands-on candy pulling activity, students in a large lecture class were provided a tangible experience to explore bond strengths using rope candy and a luggage scale. Feedback from students indicated a clear…

It is natural to interpret entropy as a measure of energy dispersion. However, the classical, phenomenological introduction to the topic, which relies on detailed analysis of Carnot engines, obscures this interpretation. Here, we propose a modification of the classical approach, which allows the basic properties of entropy to be proven without…