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Consecutive C[subscript 60] Fullerene Dissociation from Ir([eta][superscript 2]-C[subscript 60])(CO)(Cl)(PPh[subscript 3])[subscript 2] and the Oxidative Addition of Benzene
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Felix, Tamara; Cortes-Figueroa, Jose E. – Journal of Chemical Education, 2010
This laboratory activity is a mechanistic exploration of the interactions between electronically deficient organometallic compounds and solvent molecules. Simple kinetics experiments designed to explore the mechanism of C[subscript 60] fullerene-benzene exchange on Ir(([eta][superscript 2]-C[subscript 60])(CO)(Cl)(PPh[subscript 3])[subscript 2]…
Descriptors: Inorganic Chemistry, Science Activities, Science Experiments, Science Laboratories
Electrochemistry of (Dihapto-Buckminster-Fullerene) Pentacarbonyl Tungsten(0): An Experiment for the Inorganic Chemistry Laboratory, Part III
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Igartua-Nieves, Elvin; Ocasio-Delgado, Yessenia; Rivera-Pagan, Jose; Cortes-Figueroa, Jose E. – Journal of Chemical Education, 2007
Cyclic voltammetry experiments on [60]fullerene, (C[subscript 60]), and (dihapto-[60]fullerene) pentacarbonyl tungsten(0), ([eta][superscript 2]-C[subscript 60])W(CO)[subscript 5], constitute an educational experiment for the inorganic chemistry laboratory with a primary objective to teach the chemical interpretation of a voltammogram, in…
Descriptors: Kinetics, Physics, Inorganic Chemistry, Laboratories
[60]Fullerene Displacement from (Dihapto-Buckminster-Fullerene) Pentacarbonyl Tungsten(0): An Experiment for the Inorganic Chemistry Laboratory, Part II
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Cortes-Figueroa, Jose E.; Moore-Russo, Deborah A. – Journal of Chemical Education, 2006
The kinetics experiments on the ligand-C[subscript 60] exchange reactions on (dihapto-[60]fullerene) pentacarbonyl tungsten(0), ([eta][superscript 2]-C[subscript 60])W(CO)[subscript 5], form an educational activity for the inorganic chemistry laboratory that promotes graphical thinking as well as the understanding of kinetics, mechanisms, and the…
Descriptors: Learning Activities, Kinetics, Inorganic Chemistry, Thermodynamics