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Direct linkSara E. Johnson; Taylor A. Bell; Joseph K. West – Journal of Chemical Education, 2022
As an alternative to the traditional metallocene laboratory targets, students synthesize Cp[subscript 2]TiCl[subscript 2], bis([eta][superscript 5]-cyclopentadienyl)dichloridotitanium(IV), from the mildly moisture-sensitive cis-TiCl[subscript 4](thf)[subscript 2]. Air-free handling techniques are emphasized, but the (mostly) air-stable,…
Descriptors: Science Education, Chemistry, Spectroscopy, Light
Peer reviewedHorvath, Otto; Papp, Sandor – Journal of Chemical Education, 1988
States that if photochemical reactions can be followed spectrophotometrically, reactivities can be estimated by evaluating data from only one curve. Studies such a system using computerized evaluation and simulation. Uses chlorocuprate(II) complexes in acetonitrile solutions for the model systems. (MVL)
Descriptors: Chemical Analysis, Chemical Equilibrium, Chemical Reactions, Chemistry
