To improve the experimental interest and innovative ability of advanced undergraduate students, a luminescent sensing laboratory experiment with visual performance characteristics is introduced. Students have synthesized an organic hybrid cage-like europium-germanate oxo cluster with the formula of [Eu[subscript 8](phen) [subscript 2]Ge[subscript…

A laboratory class was developed and evaluated to illustrate the synthesis of metal nanoclusters (NCs) and to explain their photoluminescence properties for the case of silver. The described experiment employs a synthetic protocol that consists of two sequential phases in a single reaction pot: the reduction of silver ions into plasmonic silver…

The lifetime of the excited state of a material is essential for characterizing its photophysical and photochemical processes and substantially affects the quantum efficiencies of its luminescence (fluorescence or phosphorescence) and photo(catalytic) reactions. However, undergraduate students are much more likely to do steady-state, rather than…

Fluorescence microscopy is a useful tool that allows students to learn the principles of fluorescence visually in chemical and biological fields. However, fluorescence equipment has high purchase and maintenance costs and thus may not be available in educational institutions or insufficiently funded laboratories. In this study, a microscope stage…

Instructive, inexpensive, and environmentally friendly laboratory syntheses of two highly luminescent copper(I) complexes CuI(PPh[subcript 3])[subscript 2](py[superscript R]) (py[superscript R] = pyridine, 4-cyanopyridine) are described for second-year/upper-division undergraduate inorganic chemistry students. Both complexes exhibit bright…

The methodology and mathematical treatment of several classic multivariate methods for the analysis of spectroscopic data is demonstrated in a straightforward way that can be used as a basis for teaching an undergraduate introductory course on chemometric analysis. The multivariate techniques of classical least-squares (CLS), principal component…

Time-resolved luminescence lifetime measurements are an important photophysical technique. However, access to this technique at the undergraduate level is limited by the expense of the instrumentation needed to create the well-defined light pulses required to measure the luminescence decay of an excited state molecule. We present here an…

A low-cost and portable colorimeter was constructed featuring a low-voltage programmable color light sensor-to-frequency converter, a CMOS 8-bit microcontroller, and an LCD display. The instrument has successfully facilitated the introduction and application of spectroscopy to groups of middle school, high school, and undergraduate students. A…

We developed a simple, cost-effective, and eco-friendly method to synthesize gold nanoclusters (AuNCs) with red fluorescence. The experiment was performed using HAuCl[subscript 4], egg white, Na[subscript 2]CO[subscript 3] (known as soda ash or washing soda), and a microwave oven. In our experiment, fluorescent AuNCs were prepared within a…

The use of different types of stains in the quantification of proteins separated on gels using electrophoresis offers the capability of deriving good outcomes in terms of linear dynamic range, sensitivity, and compatibility with specific proteins. An inexpensive, simple, and versatile lighting system based on liquid crystal display backlighting is…

A simple and cost-effective laboratory experiment is described that extracts protoporphyrin IX from brown eggshells. The porphyrin is characterized by UV-vis and fluorescence spectroscopy. A chemiluminescence reaction (peroxyoxalate ester fragmentation) is performed that emits light in the UV region. When the porphyrin extract is added as a fluor…

A simple and straightforward synthesis of a tetranuclear copper(I)-pyridine-iodide cluster is described as a laboratory experiment for advanced inorganic chemistry undergraduate students. The product is used to demonstrate the fascinating and visually impressive phenomenon of luminescence thermochromism: exposed to long-wave UV light, the…

Fluorescence and phosphorescence are two forms of photoluminescence used in modern research and in practical applications. The early observations of these phenomena, before the emergence of quantum theory, highlight the investigation into the mechanism of light emission. In contrast to incandescence, photoluminescence does not require high…

A two-period organic laboratory experiment that includes fluorescence sensing is presented. The pH-sensitive sensor MorphFl is prepared using a Mannich reaction between a fluorescein derivative and the iminium ion of morpholine. During the first laboratory, students prepare MorphFl. The second session begins with characterizing the sensor using…

We describe the use of acrylic tanks (400 x 450 x 27 mm) for visualization of chemical demonstrations in aqueous solutions. Examples of well-suited demonstrations are oscillating reactions, pH indicators, photochemical reduction of Lauth's violet, and chemoluminiscent reactions. (Contains 1 figure.)