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ERIC Number: EJ1445105
Record Type: Journal
Publication Date: 2023-Aug
Pages: 6
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: EISSN-1938-1328
Available Date: N/A
Quinacridone Red and Violet: An Infrared Surprise
Journal of Chemical Education, v100 n8 p3044-3049 2023
Quinacridone red and violet are visually different colors, an observation confirmed by their visible reflectance spectra and CIE L*a*b* coordinates. However, their IR spectra are extremely similar. Though chemically identical, the two quinacridones are polymorphs. In this experiment, designed for and tested by nonscience majors, the pigments are extracted from oil paints with hexane in a short procedure involving sonification and centrifugation. ATR-FTIR spectra of the recovered brilliantly colored powders reveal the presence of a calcium carbonate filler in one of the two paints. Factoring out the carbonate bands, the spectra are nearly identical. Students must reconcile the evidence of color and the evidence of the spectra.
Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Descriptive
Education Level: Higher Education; Postsecondary Education
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A
Author Affiliations: N/A