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Harrell, Mary L.; Bergbreiter, David E. – Journal of Chemical Education, 2017
The use of [superscript 1]H NMR spectroscopy to analyze the number-average molecular weight of a methoxy poly(ethylene glycol) (MPEG) and an acetate derivative of this MPEG is described. These analyses illustrate NMR principles associated with the chemical shift differences of protons in different environments, NMR integration, and the effect of…
Descriptors: Spectroscopy, Organic Chemistry, Scientific Concepts, Concept Teaching
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Bergbreiter, David E.; Mijalis, Alexander J.; Fu, Hui – Journal of Chemical Education, 2012
Reversible polymer dehydration and precipitation from water due to the unfavorable entropy of hydration is examined using a melting-point apparatus. The thermoresponsive lower critical solution temperature (LCST) behavior of poly(N-isopropylacrylamide) (PNIPAM) is responsible for these effects. An experiment is described that allows students to…
Descriptors: Chemistry, Plastics, Scientific Concepts, Science Instruction