The use of animated concept mapping (ACM) has been linked to an innovative learning skill when conducting students' guidance of 4 corresponding reasoning processes in electrochemistry. This research aims to establish a new perspective with ACM cognitive reasoning to broaden students' individual developments of problem-solving skills. It is followed by a quasi-experimental approach of pre-tests, post-tests and retention-tests designed for 274 qualified college students in Taiwan. All data collected from students' learning performances and feedback is further analyzed by means of achievement covariance, t-tests and one-way ANOVA. Analytical results reveal that ACM facilitates learning comparisons and out-performances in two groups of students in different post-test and retention-test scores. Students' positive feedback and learning disposition also provide the predominant advantage for participants' successful reasoning processes. Pedagogical implications suggest that ACM learning performances result in more significant collaborative reasoning.