Regioselectivity in hetero Diels-Alder reactions can be observed in a simple reaction between a nonsymmetrical heterodiene and an unsymmetrical heterodienophile. A 9 h and easy to implement laboratory experiment is described, in which students can observe the regioselectivity of inverse "electron-demand" hetero Diels-Alder reactions of…

Typical laboratory exercises for undergraduate organic chemistry students involve bulk phase reactions with work up of product. In this study, students performed accelerated versions of the Katritzky reaction of para-substituted anilines with pyrylium salts in three ways: (i) by dropcasting reagents onto a paper surface and allowing solvent to…

The topic of chemistry safety was included at the margins of traditional chemistry education in China. In order to understand the concerns of the safety issues based on the new chemistry curriculum in the mainland China secondary school, this study analyzed old and new secondary chemistry curriculum standards via the Natural Language Processing…

Einstein's relation between mass and energy is perhaps the most famous equation of Physics. Despite its simplicity, the meaning of E[subscript 0] = mc[superscript 2] is not easy to grasp. Furthermore, its traditional derivations rely either on the integral of "momentum," on properties of electromagnetic radiation, or even on the…

When the thermal expansion of water is discussed in school or university lessons, functional relationships are often inferred without considering measurement uncertainties. Moreover, in some learning materials, the goal of experimentation and the experimental setup do not match. This creates the wrong picture of scientific practice. In this…

This work documents the collaboration between the Physics department of the University of Calabria and some schools of the region in a project devoted to recovering disused instrumentation in school laboratories. The project has been conceived as a workplace experience for the students, i.e. a learning experience in a real work place. In Italy,…

In order to introduce students to the fascinating field of femtochemistry, we propose here a practical laboratory training course conceived for second-year master's students in chemistry. We describe the use of a broadband femtosecond transient absorption (pump-probe) experiment for monitoring a fast light-triggered chemical reaction in solution.…

Safe and high-quality water is essential from both the health and environmental perspectives. Water quality is so important that the United Nations has included water in the 17 Sustainable Development Goals of the 2030 Agenda for Sustainable Development. Thus, the adequate control and treatment of water are necessities. These tasks must be…

A modular experiment for upper-level undergraduate students is presented, featuring the product cycle and process evaluating the quality and quantity of biodiesel obtained from a microalgae feedstock grown under carbon-supplemented and nutrient-deprived conditions. Batch reactors are used to cultivate and harvest microalgae, which undergo…

The combination of organic synthesis and analytical chemistry into a related laboratory experiment is an excellent demonstration of the utility of making a compound to then be used further. Herein we describe an undergraduate laboratory experiment that involves the straightforward synthesis of an internal standard, ethyl 6-acetyloxyhexanoate, for…

A safe, convenient, and environmentally benign laboratory experiment for the synthesis of biodiesel from six kinds of vegetable oils has been developed for the introductory organic chemistry laboratory. The experiment uses ultrasonic irradiation in the presence of a base catalyst at room temperature and atmospheric pressure. Because of safer and…

To understand critical problems associated with solid waste and its consequences for the environment, a laboratory experiment is presented on the synthesis of aluminum-based metal-organic framework (MOF) MIL-53(Al) from household waste (PET bottles and aluminum foil/can), for undergraduate students of chemistry. This work is designed to teach…

The implementation of an integrated approach to upper-level undergraduate chemistry laboratory instruction that incorporates student choice both in the selection and sequencing of the experimental work is presented. The approach involves combining laboratory work in several traditional subdisciplinary areas of chemistry in a single course.…

In order to introduce the concept of covalent organic frameworks (COFs), an important class of predictable crystalline porous polymers, an integrated laboratory experiment for advanced organic chemistry students is reported. The importance of these kind of polymers and their multiple applications are presented as a part of key concepts in polymer…

The introduction of the Wireless Smart Cart by PASCO scientific in April 2016 has ushered in a paradigm shift in the design and implementation of low-cost undergraduate physics and engineering laboratory experiments. The use of smartphones in experimental physics is by now widely accepted and documented. The smart cart in combination with…