Wheat powdery mildew is an important fungal pathogen of wheat with an obligatory biotrophic lifestyle (a parasite that can only develop on a living host). We investigated the genetics of this host-pathogen interaction by using phenotyping and PCR assays to detect genes in both wheat and powdery mildew, which are known determinants of the outcome…

Photochemical reactions are initiated by the absorption of light, triggering the chemical reactions and resulting in the formation of products. These reactions are generally performed using a freely available renewable source of energy-solar energy. Solar simulators mimic both the ultraviolet and visible regions of sunlight and hence can serve as…

The discovery of ferrocene, Fe(C[subscript 5]H[subscript 5])[subscript 2], in the 1950s sparked the development of organometallic chemistry including metallocene compounds. Shortly after the isolation of ferrocene, the analogous ruthenium and osmium compounds were discovered. The preparation of ferrocene is common in undergraduate inorganic…

Metal-organic frameworks (MOFs) are a class of porous materials that are often crystalline with high surface area and structural tunability. In this laboratory experiment designed for inorganic chemistry students at the undergraduate level, students complete a two-step experiment where they will first (i) synthesize two isostructural…

Previous educational articles on microfluidic technology mainly focused on continuous microfluidics, so we set up an undergraduate laboratory experiment to introduce droplet microfluidics to students. Students can understand the concept of microfluidic channels and the principles of droplet microfluidics, prepare polydimethylsiloxane (PDMS)…

The addition of a small excess of triethyl orthoformate to an alcoholic mixture of NiCl[subscript 2]·6H[subscript 2]O and triphenylphosphine (PPh[subscript 3]) results in an increase in the typical isolated yield of [NiCl[subscript 2](PPh[subscript 3])[subscript 2]] from below 50% to over 85%. The impact of water when present in the reaction…

Lakes are artists' pigments made from colorants bound to an inert substrate, usually hydrated aluminum oxide. Before the late 19th century, lakes were made from natural pigments extracted from plants and insects, extracted either directly from the dyestuff or indirectly from waste materials generated in the manufacture of dyed textiles. The first…

Most students enter college without any exposure to polymer science, which leads to the poor understanding and slow implementation of plastic recycling programs in the United States. To address the knowledge gap in chemical recycling, we introduce a 2-part laboratory experiment that was conducted in multiple high schools and public outreach events…

Here, a relatively simple laboratory experiment of a physical pendulum, suitable for students of science and engineering in the first courses of university physics, is presented to illustrate its dynamic behavior and to determine its inertia moment. To this end, a long wooden rod of length L = 99.8 cm and cross-section radius R = 1.73 cm was used…

This experiment demonstrates that copper(II) chloride dihydrate (CuCl[subscript 2]·2H[subscript 2]O) in different solvents (acetone, isopropyl alcohol, or water) displays divergent colors and visible-near IR spectra. Both the reactions of these solutions with 2 equiv of sodium hydroxide (NaOH) and the direct solid-state reaction of CuCl[subscript…

An advanced research discovery laboratory course in inorganic chemistry has been developed to engage undergraduate students in authentic research experiences directly related to concepts and theory taught in the lecture portion of the course. The 12-week laboratory involves an initial 4 weeks of training experiments on inorganic/organometallic…

Undergraduate students of a molecular cell biology laboratory class learn basic recombinant DNA (rDNA) technology by engaging in a Genomic Library Construction Project. Significantly, in this lab project students learn experimental design strategy. The challenge for students is to determine the strategy that they can take to efficiently screen for…

NMR prediction using ChemDoodle, NMR calculation with Gaussian, and hands-on data collection using a benchtop NMR spectrometer were explored to assess their synergistic capacity in teaching NMR to organic chemistry students. Nine molecules representing functional groups commonly encountered in undergraduate organic chemistry were selected. Spectra…

This study reports an undergraduate laboratory experiment that explores the temperature-dependent kinetics of caffeine release during tea steeping by using quantitative [superscript 1]H NMR spectroscopy with a water suppression pulse sequence. Designed for introductory organic chemistry laboratory courses, the experiment emphasizes the real-world…

Spin crossover (SCO) materials that switch between two different spin states, that is, the high spin (HS) and the low spin (LS) state, with very different optical, magnetic, and structural properties offer a unique platform to understand the consequences induced by the different electronic configurations of transition metal complexes. Due to the…