The essential component of expanding an undergraduate curriculum is the inclusion of lab experiments in nanoscience and nanomaterials, which significantly impact health and the environment through their use in food, cosmetics, agriculture, and medicine. We designed a laboratory experiment based on the atomic force microscopy (AFM) analysis of the…

Teaching chemistry without access to a traditional laboratory space is an ongoing challenge that has become especially relevant because of the SARS-CoV-2 pandemic. While several remote learning options exist for covering general chemistry concepts (including kitchen-based experiments, online modules, and virtual reality), few options provide…

This experiment introduces undergraduate organic chemistry students to analysis and interpretation of Fourier transform infrared (FTIR) spectra through characterization of postconsumer plastics. Students use FTIR spectra to identify and differentiate the common recyclable polymer resins #1-6: polyethylene terephthalate (PETE), polyethylene (HDPE…

Polymer chemistry is an important subject in the undergraduate chemistry curriculum. It is required for ACS-certified degrees and significantly connects to real world issues like the plastic waste crisis. While some concepts of polymer chemistry can be incorporated into lecture courses, students' understanding of material properties and…

For the past century, humans have been increasingly dependent on plastics, but have not developed adequate disposal practices. In this lab, students are asked whether burning plastic for energy seems like a reasonable disposal technique. To answer the chemical aspects of this question, students use bomb calorimetry to quantify the combustion…

The bioinspired polymer polydopamine is synthesized and deposited on semiconductive glass substrates under different synthesis conditions (pH and oxidant type). Electrochemical methods are used to verify polymer deposition on the substrate and to examine the charge transfer properties of the obtained coatings. The presence of aromatic rings from…

Polymerization reaction media can have a profound effect on the physical properties of the resultant polymer. This phenomenon is showcased in a new experiment for the organic chemistry and polymer science teaching laboratories wherein the radical copolymerization of biobased [beta]-myrcene and dibutyl itaconate is performed using a nonhazardous…

Given the importance of self-healing polymers for chemistry education, herein, we introduce our latest research results in self-healing materials based on thioctic acid into undergraduate chemistry laboratory. In this experiment, a natural small molecule, thioctic acid (TA), and a few other commercially-available reagents have been used to make a…

We developed a multipart laboratory experiment on the synthesis of free-standing hydrogels for junior to senior undergraduate students. In this experiment series that runs over the course of multiple 3-h lab periods, small everyday objects belonging to the students are reproduced as hydrogels by first creating negative templates in thermally cured…

All-solid-state polymer electrolytes (SPEs) have been regarded as an advisible alternative for simultaneously overcoming the safety issues and high energy density demands presented in traditional lithium batteries, and they represent the development orientation of energy storage devices. This course describes the preparation of a cross-linked and…

A laboratory exercise for the synthesis of a sulfonated styrene-"co"-maleic anhydride polymer and its application as a stain blocker on nylon-6,10, is described. The effectiveness of the sulfonated polymer to prevent the conjugate base of an acid dye from staining the polyamide is demonstrated. This experiment is designed for…

The ACS Guidelines for bachelor's degrees in chemistry call for the curriculum to include polymer chemistry principles and the synthesis of different classes of macromolecules. Organic chemistry can provide an important introduction to polymer chemistry principles, and photochemically induced radical polymerization is one method for generating…

In order to introduce the concept of covalent organic frameworks (COFs), an important class of predictable crystalline porous polymers, an integrated laboratory experiment for advanced organic chemistry students is reported. The importance of these kind of polymers and their multiple applications are presented as a part of key concepts in polymer…

Microplastic contamination of the environment is a major concern but detecting such contamination presents a challenge, particularly for particles <0.1 mm in size. Community scientists and students who participated in a plankton monitoring program and routinely examined samples of seawater using brightfield microscopy, often found fragments and…

The importance of understanding factors that contribute to surface wettability is highlighted in this new organic chemistry laboratory experiment, which aims to introduce the application of organic chemistry at the interface of polymer chemistry and material science. Polydimethylsiloxane (PDMS), a hydrophobic silicon-based rubber, is polymerized…