NMR spectroscopy is a powerful spectroscopic tool that not only allows the determination of structures after synthesis, as usually explained to students of Organic Chemistry, but also is useful in many other fields such as medicine imaging, real-time industrial processes, material sciences, or metabolomics. In this experiment, students performed a…

This experiment introduces undergraduate organic chemistry students to analysis and interpretation of Fourier transform infrared (FTIR) spectra through characterization of postconsumer plastics. Students use FTIR spectra to identify and differentiate the common recyclable polymer resins #1-6: polyethylene terephthalate (PETE), polyethylene (HDPE…

Polymerization reaction media can have a profound effect on the physical properties of the resultant polymer. This phenomenon is showcased in a new experiment for the organic chemistry and polymer science teaching laboratories wherein the radical copolymerization of biobased [beta]-myrcene and dibutyl itaconate is performed using a nonhazardous…

All-solid-state polymer electrolytes (SPEs) have been regarded as an advisible alternative for simultaneously overcoming the safety issues and high energy density demands presented in traditional lithium batteries, and they represent the development orientation of energy storage devices. This course describes the preparation of a cross-linked and…

In order to introduce the concept of covalent organic frameworks (COFs), an important class of predictable crystalline porous polymers, an integrated laboratory experiment for advanced organic chemistry students is reported. The importance of these kind of polymers and their multiple applications are presented as a part of key concepts in polymer…

Microplastic contamination of the environment is a major concern but detecting such contamination presents a challenge, particularly for particles <0.1 mm in size. Community scientists and students who participated in a plankton monitoring program and routinely examined samples of seawater using brightfield microscopy, often found fragments and…

The importance of understanding factors that contribute to surface wettability is highlighted in this new organic chemistry laboratory experiment, which aims to introduce the application of organic chemistry at the interface of polymer chemistry and material science. Polydimethylsiloxane (PDMS), a hydrophobic silicon-based rubber, is polymerized…

Harmful plastic debris found on beaches and in the oceans are not limited to drinking straws or bags. There are several synthetic organic polymers that can be used to make different kinds of plastic materials and have resulted in billions of tons of waste that can reach the aquatic biome and are harmful to freshwater and marine communities as well…

An experiment for the identification of synthetic polymers and copolymers by analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) was developed and performed in the polymer analysis courses for third-year undergraduate students of chemistry with material sciences, and for first-year postgraduate students of polymer sciences. In…

Poly(phenylene vinylene) (PPV) represents an important class of conjugated, conducting polymers that have been readily exploited in the preparation of organic electronic materials. In this experiment, students prepare a PPV polymer via a facile multistep synthetic sequence with robust spectroscopic evaluation of synthetic intermediates and the…

The measurement of trace levels of bisphenol A (BPA) leached out of household plastics using solid-phase microextraction (SPME) with gas chromatography-mass spectrometry (GC-MS) is reported here. BPA is an endocrine-disrupting compound used in the industrial manufacture of polycarbonate plastic bottles and epoxy resin can liners. This experiment…

Polymer science represents an important area in industrial and research laboratories for chemists and material scientists. However, experiments involving polymers are uncommon in chemistry and material science curricula; therefore, an experiment involving polymers has been developed. This experiment has been used to teach fabrication of polymer…

This article summarizes an experiment on thin-film fabrication with layer-by-layer assembly that is appropriate for undergraduate laboratory courses. The purpose of this experiment is to teach students about self-assembly in the context of thin films and to expose students to the concepts of functional polymeric coatings. Students dip coat…

The depolymerization of the plastic polyethylene terephthalate (PET or PETE) is described in this laboratory procedure. The transesterification reaction used to depolymerize PET employs a highly efficient N-heterocyclic carbene catalyst derived from a commercially available imidazolium ionic liquid. N-heterocyclic carbenes are potent nucleophilic…

A series of experiments for undergraduate laboratory courses (e.g., organic, polymer, inorganic) have been developed. These experiments focus on understanding the regiochemistry of the conducting polymer poly(3-hexylthiophene) (P3HT). The substitution patterns in P3HTs control their conformational features, which, in turn, dictates the [pi]…