The adulteration of food products, including honeys and syrups, is of growing concern in global food markets. Detecting adulterated food products can be difficult using traditional analytical methodologies because of complex sample matrices or poor separation of key compounds. NMR is an analytical tool that circumvents some of these issues by…

A laboratory experiment has been devised to train new graduate trainees in the safe and controlled handling of air-sensitive organometallic reagents using Schlenk lines, high vacuum pumps, liquid nitrogen traps, and cannula transfers. The reaction involves the formation of air-, moisture-, and thermally sensitive 2-pyridyllithium, generated in…

With an awareness of the considerable discomfort of graduate students in grasping the crux of key concepts of voltammetry and its variants, I present an inexpensive and user-friendly hands-on setup based on the fabrication of a rotating platinum electrode to facilitate teaching the tenets and applications of hydrodynamic voltammetry (HV). Readily…

Properties of chemical substances drive a large portion of research in the sciences, but properties are very difficult to search in full text documents, and while searches in chemical information retrieval resources may help, the effective use of such resources may require considerable knowledge of the indexing and excerption policies in the…

A central theme in introductory and advanced chemical education courses pertains directly to the transfer of electrons between atoms, ions, or molecules. This article presents theoretical treatments of electron transfer with specific attention toward applying these principles to experiment. The goal is to revitalize teaching electron transfer at…

We have developed a multivariate and multidisciplinary lab experiment on the synthesis of alginate hydrogel beads of various sizes and dye encapsulation for upper-division undergraduate and graduate students. This experiment introduces students to several common concepts in polymer chemistry, materials science, and drug delivery. The experiment…

This report describes the implementation of a laboratory exercise for an advanced biochemistry or enzyme kinetics class at the undergraduate or graduate level, designed to improve understanding of protein conformational changes associated with the binding of a ligand. Students measure the fluorescence changes induced by the conformational…

The Ball Bearing High Voltage generator is a fairly simple and transparent apparatus that can serve as a tool to motivate conceptual descriptions and calculations in electrostatics that are normally presented to our students in a rather dry and matter-of-fact fashion. For example, instead of posing a problem in the typical textbook form of…

Computer vision (CV) is a subfield of artificial intelligence (AI) that trains computers to understand our visual world based on digital images. There are many successful applications of CV including face and hand gesture detection, weather recording, smart farming, and self-driving cars. Recent advances in computer vision with machine learning…

A Microsoft Excel workbook has been developed to simplify the quantitative analysis of experimentally measured titration curves for diprotic and triprotic amino acids such as glycine, arginine, histidine, and glutamate. Students perform the titration, enter the data into the worksheet, and manually adjust the resulting pK[subscript a] values to…

In this approach, formulae based mnemonics by counting lone pair of electrons (localized or delocalized) have been highlighted by innovative and time economic way to enhance interest of students' who belong to paranoia zone of chemistry for the prediction of Hybridization state of hetero atom and Aromatic, Anti aromatic, non aromatic behavior of…

The quantum mechanics of a simplified Pöschl-Teller potential in one dimension is analyzed at an elementary level. The number of bound states of this potential is determined by a parameter "l" characterizing the depth of the potential energy. The resulting collection of potentials with varying depth, as well as their ground state…

Diluting a system with metal complexes can sometimes cause free metal ions to increase in concentration. This paper describes "metal ion anti-buffering", a situation in which free metal ion concentrations rapidly increase as system dilution drives dissociation. It only occurs under excess free ligand conditions when a solution is…

As digital educational media use becomes more widespread, an opportunity exists to develop new methods to present abstract ideas to provide a more meaningful learning experience. Drawing from psychology and dynamic visualization research, new interactive tools can be thoughtfully designed but it is also necessary to establish how these media are…

This paper summarizes a project seminar in analytical chemistry that includes a method comparison approach and collaborative learning. In this project seminar, 12 students worked in four groups, each of which focused on one method for quantitative element analysis, including flame atomic absorption spectroscopy, inductively coupled plasma mass…