A laboratory project to introduce upper-level undergraduates to Pd-catalyzed C-N [sigma]-bond forming reactions is described. The exercise involves evaluation of monodentate phosphine ligands and solvents for the Buchwald-Hartwig coupling of 4-chloro-or 4-bromo-anisole with morpholine. Students gain experience in the synthesis of a biarylphosphine…

Chemometric techniques such as partial least-squares (PLS) regression have been applied with huge success to a wide array of chemical problems including multicomponent analysis of analytes in complex mixtures. Despite this, there are few examples of laboratory pedagogical exercises that involve students in the acquisition of chemical data from…

Optics is one of the subject areas in which students have difficulty learning. Establishing the right connections between the concepts of optics and daily life supports the learning of the concepts of optics. In addition, this connection increases the students' motivation to learn optical issues. In this study, three activities related to prisms…

In this paper, we report an experiment intended as a tool to introduce chemistry and materials science students to several chemical concepts through the determination of the best experimental conditions for the formation of calcium oxide (lime) from a source of high content of calcium carbonate (eggshells). Thermal gravimetric analysis (TGA),…

Stars are point-source emitters that are the closest to the definition of a blackbody in comparison to all other similar sources of radiation found in nature. Existing libraries on stellar spectra are thus a valuable resource that can be used to introduce the laws of thermal radiation in a classroom setting. In this article we briefly describe…

In this experiment, students perform an air-free synthesis of three dichlorophosphinenickel(II) compounds, NiCl[subscript 2](PPh[subscript 3])[subscript 2], NiCl[subscript 2](PCy[subscript 3])[subscript 2], and NiCl[subscript 2](DPPE), using NiCl[subscript 2]·6H[subscript 2]O and the appropriate phosphine as the precursors. These colorful nickel…

Without question, one of the most useful tools an astronomer or physicist can employ to study the universe is spectroscopy. However, for students in introductory physics or astronomy classes, spectroscopy is a relatively abstract concept that combines new physics topics such as thermal radiation, atomic physics, and the wave and particle nature of…

A public demonstration of laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) for fast and sensitive qualitative elemental analysis of solid everyday objects is described. This demonstration served as a showcase model for modern instrumentation (and for elemental analysis, in particular) to the public. Several steps were made to…

In this time of concern over climate change due to the atmospheric greenhouse effect, teachers often choose to extend relevant classroom work by the use of physical models to test statements. Here we describe an activity in which inexpensive backyard models made from cardboard boxes covered with various household transparent materials allow…

Radiation, radiation detection and radiation protection are topics in physics and its applications which generate a wide interest in the public. This interest is either generated through medical procedures, applications of nuclear energy or nuclear accidents. The technical nature of these topics usually means that they are not well covered in the…

When students are first introduced to the idea of radioactive decay, a large conceptual hurdle must be overcome. The thought that an object's age has no bearing on the chance it will "die" (decay in this case) on a particular day is completely at odds with biological notions of life and death. Through the use of a simple…

A research project for senior undergraduates of chemistry has been developed to introduce syntheses of a series of monodispersed semiconductor PbS quantum dots (QDs) and their characterization methodologies. In this paper, we report the preparation of monodispersed semiconductor PbS QDs with sizes smaller than the exciton Bohr radius using a…

First-order kinetic decay rates can be obtained by measuring the time-dependent reflection spectra of ultraviolet-sensitive objects as they returned from their excited, colored state back to the ground, colorless state. In this paper, a procedure is described which provides an innovative and unique twist on standard, undergraduate, kinetics…

Variations in the isotopic composition of elements have been widely used to study earth's climate, biosphere, and interior, and more recently to track the fate of contaminants. Within the broad range of elements that exhibit measureable isotopic variations, metal stable isotopes are increasingly applied across the biological, geological,…

In the group exercise described, students are guided through an inductive justification for the spin conservation selection rule ([delta]S = 0). Although the exercise only explicitly involves various states of helium, the conclusion is one of the most widely applicable selection rules for the interaction of light with matter, applying, in various…