Energy conversion devices such as fuel cells, metal-air batteries, and electrolyzers have been envisaged as possible solutions for cutting down the continuous accumulation of greenhouse gases resulting from the combustion of fossil fuel. The bottleneck reaction for these devices is the oxygen reduction reaction (ORR) occurring at the cathode. The…

Historically, classical thermodynamics was developed during attempts to improve the efficiency of steam engines. Those investigations led to the well-known zeroth, first, and second laws of thermodynamics. Although these laws are presented independently, linkages between the zeroth and second laws have been pointed out in the physics teaching…

Teaching and learning introductory thermodynamics has drawn considerable research attention over the last two decades, especially in several disciplines of higher education. Under particular investigation is the First Law of Thermodynamics (FLT), which offers an expression of energy conservation in thermodynamic systems, as the evidence shows that…

We report on the study of student difficulties regarding a heat engine in the context of a Stirling cycle by the method of measurement. An in-class test about a Stirling engine with a regenerator was taken by three classes, and the students were asked to perform one of the most basic activities--calculate the efficiency of the heat engine. Our…

Physical principles are involved in almost any aspect of cooking. Here we analyse the specific process of baking pizzas, deriving in simple terms the baking times for two different situations: for a brick oven in a pizzeria and a modern metallic oven at home. Our study is based on fundamental thermodynamic principles relevant to the cooking…

The article proposes a new research object for a general physics course--the vapour Cartesian diver, designed to study the properties of saturated water vapour. Physics education puts great importance on the study of the saturated vapour state, as it is related to many fundamental laws and theories. For example, the temperature dependence of the…

This study investigates the preservice elementary teachers' ability to use the components of an argument structure on a given science topic as well as the quality of the developed argument during their sophomore and senior year. In doing so, the study also aimed to discuss the effect of teacher education programs on the development of…

Small organic molecules offer a rich opportunity to discuss the interplay of chemical structure with properties such as the melting point and phenomena such as glass formation and can form the basis of fundamental considerations of structure-property relationships in macromolecules. Of particular importance are thermal transitions, specifically…

Comfort whilst camping overnight during outdoor pursuits is based on pain free and warm sleeping arrangements and is highly dependent on the performance of the sleeping bag and sleeping mat. In adventurous and challenging situations, performance can contribute to safety and expedition success. From the manufacturer's point of view, thermal…

The enthalpy of vaporization (?H[subscript vap]) of salt solutions is not easily measured, as a certain quantity of pure water has to be evaporated from a solution, at constant composition, and at a fixed temperature and pressure; then the corresponding heat input has to be measured. However, a simple bubble column evaporator (BCE) was used as a…

It is well known that heat transfer between two objects results in a positive change in the total entropy of the two-object system. The second law of thermodynamics states that the entropy change of a naturally irreversible process is positive. In other words, if the entropy change of any process is positive, it can be inferred that such a process…

This article describes the implementation and application of a metal deposition and surface diffusion Monte Carlo simulation in a physical chemistry lab course. Here the self-diffusion of Ag atoms on a Ag(111) surface is modeled and compared to published experimental results. Both the thin-film homoepitaxial growth during adatom deposition onto a…

A highly instructive, wide-ranging laboratory project in which students study the effects of various parameters on the enzymatic activity of alcohol dehydrogenase has been adapted for the upper-division biochemistry and physical biochemistry laboratory. Our two main goals were to provide enhanced data analysis, featuring nonlinear regression, and…

Wind musical instruments are affected in their intonation by temperature. We show how to account for these effects in a simple experiment, and provide results in languages accessible to both physics and music professionals.

Robust and fast methods for chemical or multiphase equilibrium calculation are routinely needed by chemical-process engineers working on sizing or simulation aspects. Yet, while industrial applications essentially require calculation tools capable of discriminating between stable and nonstable states and converging to nontrivial solutions,…