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ERIC Number: EJ1445522
Record Type: Journal
Publication Date: 2023-Nov
Pages: 9
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: EISSN-1938-1328
Available Date: N/A
Kinetics of the Color-Fading Reaction of Phenolphthalein in Alkaline Solution Studied with a Simple and Economical Device
Guan-Jie Luo; Pei-Hsuan Wu; Ming-Le Lin; Fang-Fei Chou; Jim Jr-Min Lin
Journal of Chemical Education, v100 n11 p4298-4306 2023
A simple photometric device was built to measure the kinetics of the title reaction. The device consisted of a green light-emitting diode (centered at 520 nm), a sample vial, a photodiode, and an Arduino microcontroller board. These parts were mounted on a black poly(lactic acid) holder which was manufactured by utilizing three-dimensional printing. Adequate sensitivity and dynamic range (linear detection range from 2 × 10[superscript -3] to 0.9 in absorbance, base 10) and time resolution (ca. 6 × 10[superscript -3] s) have been achieved. The time-resolved absorbance of the pink form of phenolphthalein was recorded automatically. The time scale of the forward reaction can be controlled by [OH[superscript -]]. Evidence of reaching a chemical equilibrium was observed at conditions of higher concentration of phenolphthalein and lower [OH[superscript -]]. We also demonstrated direct observation of the slow reversed reaction (taking ca. hours). Factors affecting the reaction kinetics like the ionic strength and organic solvents have also been tested. For a laboratory class, the basic goal may include the kinetics of the forward reaction and a simple description of the chemical equilibrium. If time allows, the reversed reaction (color reappearing) may be demonstrated. In a test run, the participating high school students positively agreed that this activity had increased their related ability, while a minor portion of them were less confident on more complicated knowledge items like using the Beer-Lambert law, measuring the lifetime, and knowing the evidence of the reverse reaction.
Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Descriptive
Education Level: Secondary Education; High Schools
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A
Author Affiliations: N/A