Benzoin, an [alpha]-hydroxy ketone, is stereoselectively reduced by sodium borohydride to yield hydrobenzoin, the stereochemistry of which is determined by acetalization and analysis of the derivative by NMR spectroscopy. This classical experiment has been enhanced by modern spectroscopic and computational analysis to enable students to…

The principles of process-oriented guided inquiry learning (POGIL) are applied to the analysis of the emission spectrum of atomic hydrogen. Over the course of three learning cycles, students construct the hydrogen atom's energy level diagram and assign quantum numbers using their measurements of the Balmer series plus additional information on the…

The flue gas from waste incineration power plants contains high-level zinc species that may deactivate the catalyst for selective catalytic reduction (SCR) of nitrogen oxides (NO[subscript x]) with NH[subscript 3]. A comparison experiment was designed to investigate the effect of different types and Zn/Ce molar ratios on the performance of…

Electrochemical and spectroelectrochemical techniques are very important for characterizing energy materials. In the search for new sources of renewable energy, water splitting for hydrogen production and CO[subscript 2] reduction is attracting significant attention. These applications require efficient and durable catalysts and a detailed…

All-solid-state polymer electrolytes (SPEs) have been regarded as an advisible alternative for simultaneously overcoming the safety issues and high energy density demands presented in traditional lithium batteries, and they represent the development orientation of energy storage devices. This course describes the preparation of a cross-linked and…

Quantum dots (QDs) are useful for demonstrating the particle-in-a-box (PIB) model utilized in quantum chemistry, and can readily be applied to a discussion of both thermodynamics and kinetics in an undergraduate laboratory setting. Modifications of existing synthetic procedures were used to create QDs of different sizes and compositions (CdS…

In this laboratory experiment, students performed thermogravimetric analysis (TGA) coupled with mass spectrometry (MS) of herbaceous materials (TGA-MS) and learned to analyze mass-loss curves, as well as identify common fragmentation ions. The experiment is the first one to present the application of TGA in a currently relevant topic: biomass…

While structure-property relationships are commonly developed in applications of physical organic chemistry to real-world problems at the graduate level, they have not been generally emphasized in the undergraduate chemistry curriculum. For instance, the ability to modify the energy gap between the highest occupied molecular orbital (HOMO) and the…

Semiconductors are an important class of materials; preparing ZnO nanorods allows semiconducting properties to be easily observed. The week before lab, groups of four students take 15 min to setup two fluorine-doped tin oxide glass (FTO) slides in a zinc nitrate and hexamethylenetetramine solution stored at 90°C until the next lab. Hexagonal ZnO…

FRET (Fo¨rster resonance energy transfer) involves the transfer of energy from an excited donor fluorophore to an acceptor molecule in a manner that is dependent on the distance between the two. A biochemistry laboratory experiment is described that teaches students how to use FRET to evaluate distance changes in biological molecules. Students…

The laboratory unit demonstrates a project based approach to teaching physical chemistry laboratory where upper-division undergraduates carry out a transient-absorption experiment investigating the kinetics of cis-trans isomerization of N,N-dimethyl-4,4'-azodianiline. Students participate in modification of a standard flash-photolysis spectrometer…

This study proposes a home-assembled, low-cost blue light-emitting diode (LED) photometer that uses simple and low-cost hardware and software, costing about US $150. This 425-nm wavelength photometer is controlled by an 89C51 microcontroller chip. Glucose concentration detection experiments involving enzyme coupling reactions were carried out to…

We describe recent experiments at CERN in which antihydrogen, an atom made entirely of antimatter, has been held in a magnetic minimum neutral atom trap and subjected to microwave radiation to induce a resonant quantum transition in the anti-atom. We discuss how this, the first experiment to observe an interaction between an antihydrogen atom and…

This paper describes an inexpensive experiment to determine the carbonyl stretching frequency of an organic keto compound in its ground state and first electronic excited state. The experiment is simple to execute, clarifies some of the fundamental concepts of spectroscopy, and is appropriate for a basic spectroscopy laboratory course. The…

Photochemical upconversion is a regenerative process that transforms lower-energy photons into higher-energy light through two sequential bimolecular reactions, triplet sensitization of an appropriate acceptor followed by singlet fluorescence producing triplet-triplet annihilation derived from two energized acceptors. This laboratory directly…