Xerogels, exemplified by silica gel, are substances formed by drying gels, resulting in a loss of their internal solvents. Understanding the production and properties of xerogels is crucial, owing to their widespread applications. Xerogel chemistry is widely utilized in several substances; therefore, understanding this chemistry is extremely…

The demand for sustainable synthetic methods in modern industry has been increasing rapidly due to the requirements of environmental protection and energy conservation, which has brought organic electrochemical synthesis to the forefront nowadays. Here, a two-part laboratory experiment has been designed to train undergraduates in comprehending and…

Saccharin (1,2-benzisothiazole-3-one 1,1-dioxide) is an artificial sweetener used in the food industry. It is a cheap and easily available organic compound that may be used in organic chemistry laboratory classes for the synthesis of related heterocyclic compounds and as a derivatizing agent. In this work, saccharin is used as a starting material…

The synthesis of nanomicelles in the aqueous phase on the basis of nonhazardous detergents is described where azulene and a naphthalene tetracarboximide are used in this experiment to teach the relation between structural and optical properties of organic compounds and point out possible applications. The experiment covers many aspects of…

A modified total synthesis of (S)-goniothalamin is described for an advanced course in organic chemistry. This experiment gives students an opportunity to handle organometallic reagents and perform an enzymatic kinetic resolution and a metathesis reaction, all in the same synthesis. Furthermore, students learn flame-drying techniques for the…

The straightforward large-scale synthesis and the ability to adjust the properties of polymers make polymers very attractive materials. Polymers have been used in numerous applications and an increased demand is foreseeable. However, a serious issue is the accumulation of enormous amounts of end-of-life polymers, which are currently recycled by…

A three-part experiment that leads to the synthesis of palladium(II) complex starting from a C[subscript 3]-symmetric triaminoguanidinium-based ligand is presented. In the first part, the preparation of tris-benzylidenetriaminoguanidinium chloride ([H[subscript 6]Br[subscript 3]L]Cl) by an acidic catalyzed 3-fold imine formation reaction of…

A research project for senior undergraduates of chemistry has been developed to introduce syntheses of a series of monodispersed semiconductor PbS quantum dots (QDs) and their characterization methodologies. In this paper, we report the preparation of monodispersed semiconductor PbS QDs with sizes smaller than the exciton Bohr radius using a…

Variable temperature NMR spectroscopy is used to determine the ?H° and ?S° of hydrogen bond formation in a simple diamide. In this two- or three-day experiment, students synthesize N,N'-dimethylmalonamide, dimethylsuccinamide, dimethylglutaramide, or dimethyladipamide from methylamine and the corresponding diester (typically in 50% recrystallized…

Thanks to their unique physicochemical properties (e.g., surface plasmon resonance), noble metal nanoparticles are at the cornerstone of nanotechnology. Silver triangular nanoprisms are presented here as an ideal playground to introduce students to nanochemistry concepts such as the formation of shape-controlled nanostructures. Not only a reliable…

Introducing students to a multidisciplinary research laboratory presents challenges in terms of learning specific technical skills and concepts but also with respect to integrating different technical elements to form a coherent picture of the research. Here we present a multidisciplinary series of experiments we have developed in the Electronic,…