Most chemistry students struggle with interpreting and understanding NMR (nuclear magnetic resonance) spectra and the general concepts of NMR spectroscopy. NMR spectroscopy seems to be difficult to both teach and learn. Therefore, the corresponding courses should be investigated in more detail. We conducted a survey with N = 39 German university…

A one-pot regio- and stereoselective synthesis of a dipyrromethane and a bis(indolyl)methane based on two consecutive reactions of nitrosoalkenes with pyrrole or indole, respectively, is described as an experiment to be carried out by upper-division undergraduate students in a laboratory classroom. Importantly, the ability of electrophilic…

[NiBr[subscript 2](PPh[subscript 3])[subscript 2]] and [NiBr[subscript 2](dppe)] are prepared from nickel bromide hydrate and phosphine. These brightly colored coordination compounds are then converted into the related organometallic compounds "trans"-[NiBr(Mes)(PPh[subscript 3])[subscript 2]] and [NiBr(Mes)(dppe)] (Mes =…

The contemporary Human activity utilizes huge volumes of digital data to solve efficiently multiple socio-economic, scientific and technical problems. Now the big data analysis is mainly oriented to the socioeconomic sphere with a goal to lift the profit. The science and technology to penetrate deeper in the nature of objects and systems under…

This paper describes an upper-division undergraduate exercise involving the synthesis and iodometric and infrared spectroscopic analysis of the peroxide double salt [Zn(NH[subscript 3])[subscript 4]][Mo(O[subscript 2])[subscript 4]]. Here, iodometric methods are employed to determine the peroxide content of the compound, a procedure widely used…

Students in a typical instrumental analysis course may learn more than 30 analytical techniques. There are more than 150 components associated with the instrumentation that they learn. To help students organize this large amount of information, we classified these components into four categories: sources, samples, discriminators, and detectors. In…

Colorful transitions of various acid-base indicators have been used to illustrate the concept of chemical equilibria, especially in spectrophotometric determination of the equilibrium constants or pKa values. To accommodate an online laboratory environment necessitated by the COVID-19 pandemic, this work employs color analyses from digital images…

Nuclear magnetic resonance (NMR) spectroscopy is the tool of choice for organic chemists to determine the molecular structure of organic molecules and, as a result, is a fundamental topic in the organic chemistry curriculum. A novel laboratory module has been developed to expand the scope of NMR spectroscopy beyond structure validation at the…

Triboluminescence is a fascinating phenomenon that can engage students' interest in chemistry. However, safe, cost-effective, and accessible laboratory experiments featuring highly triboluminescent substances are limited. To bridge this gap, we present a simple, rapid, semimicro test tube preparation of the visually engaging manganese complex…

Digital video (DV) is widely used in education settings; however, few researchers have explored the neurocognitive underpinnings of DV tasks. Functional near-infrared spectroscopy (fNIRS) records neurological activity in real time, is robust to movement, and provides information about cognitive load and engagement levels during authentic learning…

A suitable combined laboratory experiment can involve more chemical disciplines and form students' views on practical connections. A laboratory experiment has been prepared focusing on the adsorption of the dangerous Co(II) ion using natural adsorbents representing waste material of a polysaccharide and keratin nature. Efficiency of Co(II)…

Infrared (IR) technologies have been universally acknowledged as a valuable pedagogical tool for exploring novel and abstract scientific subjects in science education. This study explores the roles of IR images played in middle school students' Evidence-based Reasoning (EBR) process in support of the understanding of the heat radiation process.…

An experiment for the calculation of the degree of double bond conversion, after a polymerization reaction, of photopolymerizable liquid monomers using FTIR-ATR spectroscopy is reported. The experiment was successfully conducted with undergraduate students in materials engineering during the Fundamentals of Polymeric Material course. Students…

Polymer chemistry lab experiments present a unique opportunity to allow students to experience the consequences of reaction mechanisms on the properties of the resulting product. In this organic chemistry experiment, students prepared a polyamide by three different reaction mechanisms that represent step-growth and chain-growth methods of…

A green laboratory experiment has been developed in which students perform an aqueous oxidation/cycloaddition reaction to convert salicyl alcohol into a pentacyclic diepoxydione that is readily isolated by filtration. Drawing on their knowledge of periodate-mediated 1,2-diol cleavage, students propose a mechanism for the oxidation of salicyl…