The derivation for the Gibbs phase rule, provided in physical chemistry text books, often assumes that all the components are present in all the phases coexisting at equilibrium. However, very often we have situations where all the phases at equilibrium do not have all the components, the binary eutectic system being a classic example. The melt…

The transformations of electric and magnetic fields are usually introduced by viewing systems such as a long, straight current-carrying wire and a parallel plate capacitor in two different reference frames. These well-known examples show that magnetism is a necessary consequence of augmenting electrostatics with relativity. Because they require…

Torsional effects influence kinetic selectivity in a wide range of organic transformations. As such, textbooks commonly use Newman projections to illustrate the torsional effects that arise in their transition states. Unfortunately, these representations fall short when the reaction occurs "within a ring." In many cases, the torsional…

This work outlines the inadequacies of the "ions in a sea of electrons" model. Some general properties of metals are stated. A different "soft/flexible" sphere model is described. The benefits of using this other model to account for metallic properties are discussed. Equations based on the soft sphere model are used to…

An understanding of buffers is important in a variety of chemistry subdisciplines, with relevant applications to the life sciences and health profession-related fields. Here, we describe the development and implementation of a lab that involves creating a buffer solution using baby wipes and deionized water. The goal of this lab was to emphasize a…

The students in our physical chemistry course pointed out an interesting trend in the bond dissociation energies (BDEs) of successive homolytic cleavages of hydrogens from methane and water. Namely, while there is an increase in BDE from CH[subscript 4] to CH[subscript 3], there is a decrease in BDE from H[subscript 2]O to OH. In order to explain…

Preceding even the Hartree-Fock method, molecular integrals are the very foundation upon which quantum chemical molecular modeling depends. Discussions of molecular integrals are normally found only in advanced and technical texts or articles. The objective of the present article is to provide less experienced readers, or students in a…

Due to the wide and the ever-increasing strategic applications of quantum chemistry in chemical industries, it is important to introduce chemical engineering students to illustrative case studies that deploy molecular modeling in the design of reactors and derivation of thermochemical functions. Herein, we demonstrate how quantum chemical…

The objective of this examination was to determine if there were significant differences in reported levels of motivation across five teaching tasks, as well as time allocated to each teaching task, among online and onsite university-level social science faculty. One hundred thirty-six social science faculty members were allocated into two groups…

A dual-enrollment course was designed in which the elementary concepts of organic chemistry were introduced to high school students. Students were assessed at the end of the term using an American Chemical Society (ACS) standardized exam. The same exam was given to corresponding traditional on-campus sections of the same class taught by the same…

Herein we present an engaging description of the existent analogy between social distancing during the COVID-19 pandemic and the collision cross-section of particles as defined in the collisional model for a chemical reaction. In addition, the link between collision cross-sections and kinetic rate constants is thoroughly established, bridging…

Recently there has been a push for more student-centered learning in the undergraduate classroom as a way to enhance student learning outcomes. One tool utilized in many Anatomy and Physiology courses is case studies of the material being presented. These allow students to apply their knowledge to a real-world scenario they may encounter in their…

[This paper is part of the Focused Collection on Curriculum Development: Theory into Design.] A level of curricular design, called "design tactics," is identified to fill a gap in the research literature between the broad principles that guide curriculum development and the detailed writing of specific activities and lessons. The use of…

The use of synchronous remote teaching methods in two undergraduate analytical chemistry courses during the COVID-19 pandemic is described. Classes were convened using cloud-based video conferencing software, and the majority of class time involved students working in small groups on worksheets. All group activities were followed by a whole-class…

The purpose of this study was to develop two Sudoku puzzles for undergraduate students which can be utilised in the context of introductory physical science courses in order to assist them to practice SI prefixes. For this reason, SI prefixes for decimal multiples and submultiples were addressed in two separate puzzles. To test the puzzles, a case…