Discusses the problem of symmetry avoidance using water as an historical example. Uses simple pi systems for the analysis. Provides methodology and examples. Investigates two naive arguments. (MVL)

Provides the methodology put forth by Moore and Kraus to separate Co++ from Ni++ in an 8M HCl solution. Notes that cobalt(II) forms a wide variety of anionic complexes. Points out that as the solutions leave the exchange column the color bands of green, blue, and pink are easily seen. (MVL)

Describes an advanced NMR project that can be done with a 60-MHz continuous-wave proton spectrometer. Points out the main purposes are to give students experience in second-order NMR analysis, the simplification of spectra by raising the frequency, and the effect of non-hydrogen nuclei on proton resonances. (MVL)

Attempts to provide an intuitive understanding of steady state kinetics. Discusses the meaning of steady state and uses free energy profiles to illustrate and follow complex kinetic and thermodynamic relationships. Provides examples with explanations. (MVL)

Describes a method for using nuclear magnetic resonance to observe the effect of electronegativity on the chemical shift of protons in similar compounds. Suggests the use of 1,3-dihalopropanes as samples. Includes sample questions. (MVL)

Describes a laboratory technique for quantitative analysis of caffeine by an isotopic dilution method for coupled gas chromatography-mass spectroscopy. Discusses caffeine analysis and experimental methodology. Lists sample caffeine concentrations found in common products. (MVL)

The kinetics experiments on the ligand-C[subscript 60] exchange reactions on (dihapto-[60]fullerene) pentacarbonyl tungsten(0), ([eta][superscript 2]-C[subscript 60])W(CO)[subscript 5], form an educational activity for the inorganic chemistry laboratory that promotes graphical thinking as well as the understanding of kinetics, mechanisms, and the…

Described are the energetics involved in the formation of molecular hydrogen using concepts that should be familiar to students beginning the study of molecular orbital theory. Emphasized are experimental data on ionization energies. Included are two-electron atomic and molecular systems. (CW)

Defines and discusses activated complexes, transition species, and reaction intermediates in composite reactions. Stresses the importance of the precise use of language in science. (CW)

Describes a study of perceived difficulty of chemistry courses among secondary school and college students in Kenya. Concludes that organic chemistry may not be as difficult as many people believe. (CW)

Describes a simplified redox method for total iron analysis suitable for execution in a three-hour laboratory period by general chemistry students. Discusses materials, procedures, analyses, and student performance. (CW)

Describes a laboratory experiment to determine the rate law for a substitution reaction of a transition metal. Derives the corresponding rate law from the accepted mechanism for the reaction using the steady state approximation and determines the conditions under which the two agree. (CW)

Proposed is a flow-chart and related formulas to obtain expressions for the derivatives of the old thermodynamic function in terms of new variables, the new function and its derivatives, and derivatives of the old function, involving only measurable quantities. (CW)

Presents a review focusing on techniques and their application to the analysis of geological and inorganic materials that offer significant changes to research and routine work. Covers geostandards, spectroscopy, plasmas, microbeam techniques, synchrotron X-ray methods, nuclear activation methods, chromatography, and electroanalytical methods.…

Describes an experimental procedure to acquaint inorganic chemistry students with stereochemical concepts using tris-(2,3-butanediamine)cobalt(III). Notes two isomeric forms exist and both form metal chelates. Separation is accomplished by chromatography and analysis is by NMR and infrared spectroscopy. Provides spectra of isomers. (MVL)