Problem-based learning (PBL) is an acclaimed educational concept for laboratory teaching in chemistry, which significantly affects learner motivation. A central aim of PBL is to overcome educational problems with "cook-book" laboratories. For example, when students receive experimental instructions and apply the instructions similar to…

The catalytic hydrogenation of alkenes and alkynes is an important part of the undergraduate chemistry curriculum and is a fundamental process in chemical industry. Inquiry-based laboratory activities are presented that investigate the hydrogenation of alkynes on a nanoparticle palladium surface to form alkenes, which go on to form alkanes. Alkyne…

A laboratory experiment that involves the synthesis, characterization, and application exploration of a metal-organic framework (MOF) has been developed for first-year undergraduates in the Faculty of Engineering at National University of Singapore. The desired MOF material was prepared from commercially available reagents in a facile…

Single-type, 6-fold symmetrically grooved, and commercially accessible interlocking disks (ILDs) have been used for modeling of sp[superscript 2] hybridized carbon-based nanoarchitectures and complex polyhedral and reticular material models. In the case of the carbon-based nanoarchitectures, we showcase that the primary ILDs can be directly used…

The Leidenfrost nanochemistry synthesis of gold colloids was introduced in this "Journal" as an advanced method to synthesize gold nanoparticles during an undergraduate nanochemistry research project. When trying to repeat these experiments in the laboratory, we experienced difficulties in the synthesis of the gold nanoparticles since…

One of the more difficult concepts introduced in the first-year undergraduate course, general chemistry, is that of chirality. Typically, left and right hands are the common, macroscopic objects of reference used to demonstrate the quality of being nonsuperimposable, followed by the use of a mirror and molecular models, to illustrate molecular…

An experimental approach to chemistry is a more meaningful way to learn than the use of textbooks alone. Working in the laboratory helps students understand basic concepts through their active engagement. Here, we present a series of inexpensive and environmentally friendly laboratory exercises on acid-base equilibrium. Their difficulty level is…

Experimental methods for determining 3-D atomic structures, such as crystallography, are rarely taught in the undergraduate curriculum, yet are considered to be the norm for 3-D structure determination in a research setting. Although a fully physical understanding of crystallography takes years of practice, practical applications and basic…

A research-style laboratory experiment for advanced undergraduate students is described, which includes the synthesis, characterization, and properties (porosity, stability, amphipathy) testing of the composite [Cu[subscript 2](BTC)[subscript 4/3](H[subscript 2]O)[subscript 2][subscript 6][HPW[subscript 12]O[subscript 40]·(C[subscript…

Despite the growing popularity of cyclic voltammetry, many students do not receive formalized training in this technique as part of their coursework. Confronted with self-instruction, students can be left wondering where to start. Here, a short introduction to cyclic voltammetry is provided to help the reader with data acquisition and…

Laboratory experiments that offer interdisciplinary experiences for students are appealing and are increasingly popular additions to undergraduate chemistry curricula. Students can capitalize on their knowledge of multiple areas of chemistry while working through an application, and this fosters the development of progressive problem-solving…

Inorganic Chemistry teaches students the concept that modifications to ligand structures, especially the donor properties, can have a drastic impact on the reactivity and stability of the metal complexes. Experiments described here reinforce this concept through the investigation of two tetradentate ligands derived from…

This work outlines the inadequacies of the "ions in a sea of electrons" model. Some general properties of metals are stated. A different "soft/flexible" sphere model is described. The benefits of using this other model to account for metallic properties are discussed. Equations based on the soft sphere model are used to…

The ability to perform air-free chemistry and catalytic reactions on an NMR tube scale are valuable skills in chemistry and not often included in undergraduate chemistry curriculum. This laboratory experiment provides students experience in synthesizing the metal complex, Ni(dcpe)(CH[subscript 3]CN)[subscript 2](BF[subscript 4])[subscript 2] (dcpe…

A virtual reality (VR) session was introduced to an advanced inorganic chemistry class, a class available to junior and senior undergraduate students at the University of California, Los Angeles. The VR session helped the students to learn complicated aspects of metal coordination chemistry and molecular orbitals via an immersive three-dimensional…