There is a disconnect between the cutting-edge research done in academic laboratories, such as nanotechnology, and what is taught in undergraduate laboratories. In the current undergraduate curriculum, very few students get a chance to do hands-on experiments in nanotechnology-related fields, most of which are through selective undergraduate…

Nuclear magnetic resonance (NMR) spectroscopy has become a cornerstone tool for studying a variety of molecular features in advanced chemistry laboratories. In this experiment, students prepare a pyrrole-[beta]-amide via a one-pot, three-step synthesis and use NMR spectroscopy to confirm its molecular structure. In addition, variable temperature…

Green chemistry metrics and life-cycle analysis (LCA) were used to assess inefficiencies in two current organic chemistry experiments conducted in third-year organic chemistry to synthesize ("E")-stilbene from benzaldehyde. An alternative Wittig-based, greener, one-pot experiment using the same starting material was selected as a vehicle…

A research-style laboratory experiment for advanced undergraduate students is described, which includes the synthesis, characterization, and properties (porosity, stability, amphipathy) testing of the composite [Cu[subscript 2](BTC)[subscript 4/3](H[subscript 2]O)[subscript 2][subscript 6][HPW[subscript 12]O[subscript 40]·(C[subscript…

This work reports the first use of rubber latex waste as the hydrophobic reagent for a low-cost, simple, and rapid fabrication of a paper towel-based experimental device (PTED) with a circular design of 5 mm to demonstrate the factors affecting chemical equilibrium; this serves as a user-friendly means for a laboratory experiment. The illustration…

Error analysis consumes much of the focus in introductory physics labs. Catastrophic cancellation is a spike in error that occurs when subtracting two measurements of roughly equal magnitude. Often termed "loss of significance" or "subtractive cancellation," this effect can easily relegate experimental results to utter…

Purpose: The contextual variability of stuttering events makes it difficult to reliably elicit stuttered speech in laboratory settings. As a result, studies that compare stuttered versus fluent speech are difficult to conduct and, thus, are limited in the literature. The purpose of the current study is to describe a novel approach to elicit…

Fast, reliable, well-resolved latent fingerprints can be planted by applying a thin coating of a 50:50 mixture of hand lotion and food-grade protein powder. Fingerprints can be revealed with iodine fuming or ninhydrin staining. This low-cost alternative to commercial latent print pads can be used in a variety of classroom or public settings where…

Introducing chemical equilibrium concepts in undergraduate general chemistry promotes improved understanding of chemical reactions. We have developed an engaging laboratory experiment exploring the equilibrium of cobalt complexation in alcohols using UV-vis spectroscopy and successfully implemented in a large general chemistry class of 378…

A contemporary undergraduate laboratory experiment incorporating parallel microscale experimentation was developed for the well-defined palladium catalyzed Suzuki-Miyaura cross coupling of 4-fluorophenylboronic acid with both 4-chloro- and 4-bromoanisole using 11 diverse phosphine ligands and one ligandless control. This laboratory introduces…

This paper describes the development of a light polarization experimental apparatus for a remote laboratory. The apparatus had been developed by controlling the analyzer rotation using a stepper motor controlled via the Arduino. Device control and data acquisition applications were developed with LabVIEW which provides remote control panel…

There is an increasing need for research chemists and biochemists to have a basic familiarity with computer programming. Adding programming content to already crowded STEM undergraduate curricula, however, can be challenging. When programming content is introduced within the chemistry curriculum, it is most often incorporated into upper division…

An experimental approach to chemistry is a more meaningful way to learn than the use of textbooks alone. Working in the laboratory helps students understand basic concepts through their active engagement. Here, we present a series of inexpensive and environmentally friendly laboratory exercises on acid-base equilibrium. Their difficulty level is…

This paper describes and assesses the impact of a new upper-level "scholarly" laboratory model that is part of a four-year scaffolded research skills curriculum at a Carnegie Bachelor's institution. In this scholarly lab model, students gain the "tools" of a discipline in a first-semester laboratory and engage in the scholarly…

A new project-based laboratory (PJBL) was developed for general chemistry students to tackle the steps involved in chemical water quality analysis using an accessible, real-world hydrologic system (the lakes of the Lower Grand Coulee, Washington). This PJBL was developed in a joint general chemistry and environmental geology course by a…