[superscript 31]P{[superscript 1]H} nuclear magnetic resonance spectroscopy is a particularly useful tool for studying the reactions of P-donor ligands such as phosphines and phosphites with transition metals and other Lewis bases because the reactions take place on the nonbonding pair of electrons on the phosphorus. In addition, [superscript 31]P…

An experiment involving a moisture-sensitive synthesis and spectroscopic characterization suitable for the advanced inorganic laboratory course is presented. The acid-base complex ammonia borane (AB) is synthesized from the heterogeneous reaction between sodium borohydride and finely ground ammonium sulfate in tetrahydrofuran solvent. AB is…

The social distancing measures introduced to prevent the spread of COVID-19 have led to the rapid redesign of chemistry instruction in higher education from face-to-face to online delivery. The design, implementation, and evaluation of a redeveloped undergraduate level course on catalysis which was delivered to 188 students (including 22 natural…

Magnetic iron oxide nanoparticles were synthesized and stabilized using ammonium cations or poly(vinyl alcohol) to produce amazing materials such as safer aqueous ferrofluids, ferrogels, ferromagnetic inks, plastics, and nanopowders illustrating how versatile materials can be produced just by simple modifications. The synthesis is fast, reliable,…

The American Chemical Society-Examinations Institute (ACS-EI) released the first ACS Foundations of Inorganic Chemistry Examination in 2016 to better address the two generalized types of inorganic chemistry courses (i.e., at the foundation or second/third-year level and the indepth or third/fourth-year level). The ACS Inorganic Chemistry Exam that…

Here we share results from a larger study of professional development (PD) provided to faculty at Research I Urban University (RIUU), where STEM faculty modeled active learning strategies and provided ready-to-use STEM materials to teaching staff. Data from 94 STEM faculty, who comprised 27% of the total participants (N = 340), demonstrated a…

A research-based inorganic chemistry laboratory course is described. Using the defined protocol of a course-based undergraduate research experience (CURE), students undertake a self-designed research project to identify new catalysts for the dehydrogenation of ammonia borane. Students select ligands and metals, prepare and characterize catalysts…

Creating instructional activities and assessments that align with expected learning outcomes can improve student learning. Communicating learning expectations to students may lead to better student performance and an increase in student perceptions of the fairness of the assessment tools. One tool for communicating learning outcomes is the…

Despite recent interest in online learning, systematic comparisons of online learning environments with traditional classroom environments are limited, particularly in the sciences. Here, we report on a systematic comparison of an online and face-to-face classroom for a sophomore-level, lecture-only introductory inorganic chemistry course that is…

Inorganic polymers can be introduced in a variety of undergraduate courses to discuss concepts related to polymer chemistry. Inorganic polymers such as silicates and polysiloxanes are simple materials that can be incorporated into an introductory or descriptive inorganic course. Polymers based on inorganic carbon, including diamond and graphite,…

The presentation of d-orbital splitting diagrams for square planar transition metal complexes in textbooks and educational materials is often inconsistent and therefore confusing for students. Here we provide a concise summary of the key features of orbital splitting diagrams for square planar complexes, which we propose may be used as an updated…

Synthesis of quantum dots is a valuable experiment for demonstration and discussion of quantum phenomena in undergraduate chemistry curricula. Recently, a new class of all-inorganic perovskite quantum dots (QDs) with a formula of CsPbX[subscript 3] (X = Cl, Br, I) was presented and attracted tremendous attention. Here we adapt the synthesis of…

Electronic spectra often exhibit vibronic structure when vibrational and electronic transitions occur in concert. Theory reveals (1) that orbital symmetry considerations determine specific roles played by the nuclear degrees of freedom and (2) that the vibrational excitation is often highly regiospecific, that is, attributable to an identifiable…

The radioactive nature of technetium is discussed using a combination of introductory nuclear physics concepts and empirical trends observed in the chart of the nuclides and the periodic table of the elements. Trends such as the enhanced stability of nucleon pairs, magic numbers, and Mattauch's rule are described. The concepts of nuclear binding…

ACS Examinations provide a lens through which to examine historical changes in topic coverage via analyses of course-specific examinations. This study is an extension of work completed previously by the ACS Exams Research Staff and collaborators in general chemistry, organic chemistry, and physical chemistry to explore content changes in the…