Discusses how the frequency domain (line widths) and time domain (coherent optical transients) are related to the concept of transverse relaxation time in the study of high resolution optical spectroscopy. (HM)

Highlights several analytical techniques that are being used in state-of-the-art clinical labs. Illustrates how other advances in instrumentation may contribute to clinical chemistry in the future. Topics include: biosensors, polarization spectroscopy, chemiluminescence, fluorescence, photothermal deflection, and chromatography in clinical…

Describes a method for demonstrating absorption spectra of intensely colored solutions using a mounted grating and a specially designed cell. Allows a student to compare the spectrum of a white light source directly with the same light modified by an absorbing spectrum. Uses acrylic tubing to make the cell. (MVL)

Reports that although excitation at 337nm is less than optimal, detection limits in the range 1-100pg/ml were found. Provides a calibration curve and results for seven organic compounds. (MVL)

Describes a photochemistry experiment designed to introduce photochemical techniques and experience free radical chemistry. Selects Nuclear Magnetic Resonance spectroscopy for the analysis. This activity is suggested for use in an upper level undergraduate organic course. (MVL)

A laboratory experiment is presented for the upper-level undergraduate physical chemistry curriculum in which the ternary phase diagram of water, 1-propanol and n-heptane is measured using proton nuclear magnetic resonance (NMR) spectroscopy. The experiment builds upon basic concepts of NMR spectral analysis, typically taught in the undergraduate…

This unit on atomic structure is one of 10 first year units produced by the Independent Learning Project for Advanced Chemistry (ILPAC). The unit consists of two levels. Level one focuses on the atomic nucleus. Level two focuses on the arrangement of extranuclear electrons, approaching atomic orbitals through both electron bombardment and spectra.…

The first part of this paper addresses the following topics: (1) the usefulness of microcomputers; (2) applications for microcomputers in analytical chemistry; (3) costs; (4) major microcomputer systems and subsystems; and (5) which microcomputer to buy. Following these brief comments, the major focus of the paper is devoted to a discussion of…

Discusses the range of wavelengths of the electromagnetic spectrum considered to be the visible portion. Describes a demonstration designed to help students understand the relation between the wavelength measurements on a spectrophotometer such as the Spectronic 20 and the actual colors of light being used. (TW)

Discusses electron-loss spectroscopy and the experimentally observed excitation energies in terms of qualitative MO theory. Reviews information on photoelectron spectroscopy and electron transmission spectroscopy and their relation to the occupied and unoccupied orbital levels. Focuses on teaching applications. (ML)

Reports on some of the discoveries over the last quarter century regarding quasars including spectra and energy sources, formation and evolution, and cosmological probes. Describes some of the fundamental mysteries that remain. (CW)

Describes the use of spectroscopy and the redshift to measure how far an object is by measuring how fast it is receding from earth. Lists the most distant quasars yet found. Tables include "Redshift vs. Distance" and "Distances to Celestial Objects for Various Cosmologies." (CW)

Describes a series of experiments (intended to approximate the research experience) investigating the reaction of ferrocenylmethylation with aniline. Students carry out reactions in nitrogen atmosphere, identify products by nuclear magnetic resonance spectroscopy and propose mechanisms and structures for reactions. Gives procedures for each…

Describes an apparatus (called the "Rainbow Cup") used for demonstrating the colored rings produced by constructive interference in soap films. Discusses construction of the Rainbow Cup and gives hints for its use in the classroom, especially in relation to classroom humidity. (JM)

Background information, procedures, and typical results are provided for a three-part experiment involving reactions of potassium thiocynate (KNCS) with sulfuric acid. The experiment represents the final stage of structured work prior to students' research projects during their final year. (JM)