Presents an experiment in which color is used as an additional characteristic when purifying and identifying crystals of two soluble salts obtained from a metathesis reaction. Indicates that the experiment has been used with both nonmajors and inorganic chemistry students in at least their third term. (JN)

Discusses danger of explosions with molten salts baths, commonly used as heat-transfer media. One such explosion involved use of a bath containing 3-lb sodium nitrite and 1-lb potassium thiocyanate. Although most commercially available mixtures for heat transfer contain oxidizers, a reducer (thiocyanate) was included which possibly triggered the…

Thermal features of and beneath the surface of a sample can be detected and imaged with a thermal-wave microscope. Various methodologies for the excitation and detection of thermal waves are discussed, and several applications, primarily in microelectronics, are presented. (Author)

Desorption ionization (DI) is used to obtain mass spectra of molecules whose vaporization by heating may lead to thermal degradation. Discusses DI techniques, characteristics of DI mass spectra, ion production, current applications of DI in mass spectroscopy, developments in DI, and prospects for future evolution of new DI techniques. (Author/JN)

The kinetic of the Jaffe reaction with picrate ion selective electrode (ISE) and a kinetic method for determining creatinine in urine is presented. The experiment could be used to familarize students with the application of ISE in kinetic studies and chemical analysis. (Author/JN)

Describes fluorescence experiments demonstrating that emitted light is at longer wavelengths than absorbed light and that fluorescence decays rapidly when the source of excitation is removed. Systems whose acidic and basic forms have different fluorescent characteristics are used to demonstrate fluorescence visible and invisible to the naked eye.…

Background information and procedures are provided for experiments in which the zinc and strontium content in bones (fossils and/or fresh mammalian samples) is analyzed to determine relative amounts of animal and vegetable foods consumed by an individual during its lifetime. (JN)

Points out that excellent results are obtained using an air-natural gas flame in atomic absorption experiments rather than using an air-acetylene flame. Good results are obtained for alkali metals, copper, cadmium, and zinc but not for the alkaline earths since they form refractory oxides. (Author/JN)

Reactions of phenolphthalein with sodium hydroxide and sulfuric are discussed. Also discusses the sulfonation of phenolphthalein, listing experimental results related to the sulfonation reaction. (JN)

Provides background information, procedures, and results of an undergraduate physical chemistry experiment on the polarization of absorption spectra of cyanine dyes in stretched polyvinyl alcohol films. The experiment gives a simple demonstration of the concept of linear dichromism and the validity of the TEM method used in the analyses. (JN)

Three experiments demonstrating the feasibility of encapsulating liquids within a starch matrix are described, including encapsulation of linseed oil using the zanthate method and of turpentine and butylate using the calcium adduct procedure. Encapsulated materials, including pesticides, are slowly released from the resulting matrix. Considers…

Background information, laboratory procedures, and discussion of results are provided for syntheses of cobalt (III) complexes, I-III, illustrating three possible bonding modes of glycine to a metal ion (the complex cations II and III being linkage/geometric isomers). Includes spectrophotometric and potentiometric methods to distinguish among the…

Laboratory procedures, background information, and discussion of experimental results are provided for the preparation of Thallium (I) Pentacyanocobaltate (II). The preparation of this pale green salt is carried out in an aqueous medium. (Author/JN)

Background information, laboratory procedures, and discussion of results are provided for the synthesis and chemiluminescence of adamantylideneadamantane-1,2-dioxetane (I). Results provided were obtained during a normal junior level organic laboratory course. All intermediates and products were identified using routine spectroscopic analysis.…

Background information, laboratory procedures, and discussion of results are provided for experiments designed to familiarize students with the biochemistry of nicotinamide coenzymes and the chemistry involved in their reactions. In addition, students are exposed to ultraviolet (UV)-spectroscopy as a tool for investigating reaction mechanisms in…