The lifetime of the excited state of a material is essential for characterizing its photophysical and photochemical processes and substantially affects the quantum efficiencies of its luminescence (fluorescence or phosphorescence) and photo(catalytic) reactions. However, undergraduate students are much more likely to do steady-state, rather than…

This paper describes an upper-division undergraduate exercise involving the synthesis and iodometric and infrared spectroscopic analysis of the peroxide double salt [Zn(NH[subscript 3])[subscript 4]][Mo(O[subscript 2])[subscript 4]]. Here, iodometric methods are employed to determine the peroxide content of the compound, a procedure widely used…

Capstone teaching laboratory activities can serve as a crucial part of the undergraduate learning experience. With this in mind, a laboratory activity that combines synthesis and multiple characterization techniques has been developed for an upper-division, laboratory-based inorganic course. Complexes of Cu(II) and Ni(II) of the amino acid glycine…

Introductory physics laboratory experiments have typically been employed to reinforce classroom instruction instead of teaching students experimental design. Recent research has shown that lab experiments that focus on experimental practices are more effective at teaching students physics concepts. The experiment described in this paper has been…

As the field of educational neuroscience continues to grow, questions have emerged regarding the ecological validity and applicability of this research to educational practice. Recent advances in mobile neuroimaging technologies have made it possible to conduct neuroscientific studies directly in naturalistic learning environments. We propose that…

The bromination of six isomeric alcohols is adapted to a discovery-based organic chemistry laboratory experiment, whereby students are provided an alcohol starting material and are charged with determining the product or product mixture produced using relevant spectroscopic data. The experiment solidifies NMR analysis skills while reinforcing the…

This laboratory experiment introduces upper-division undergraduate analytical chemistry students to liquid chromatography-tandem mass spectrometry (LC-MS/MS) in a forensic application: the analysis of cocaine and metabolites of cocaine in simulated serum ostensibly from drug overdose victims. For this investigation, students developed the…

Infrared (IR) spectroscopy is a vibrational spectroscopic technique useful in chemical, pharmaceutical, and forensic sciences. It is essential to identify chemicals for reasons spanning from scientific research and academic practices to quality control in companies. However, in some university degrees, graduate students do not get the proficiency…

A laboratory project to introduce upper-level undergraduates to Pd-catalyzed C-N [sigma]-bond forming reactions is described. The exercise involves evaluation of monodentate phosphine ligands and solvents for the Buchwald-Hartwig coupling of 4-chloro-or 4-bromo-anisole with morpholine. Students gain experience in the synthesis of a biarylphosphine…

Iodonium zwitterions are hypervalent iodine compounds in which the iodine center binds to two substituents and carries a positive formal charge which is compensated by a negative charge within the same molecule. Under thermodynamic conditions, iodonium zwitterion sallow concerted nucleophilic aromatic substitutions to be performed, followed by…

This is an easy and cheap experiment where chemistry Masters students can evaluate the role of some metal ions (i.e., Cu[superscript II] and Mn[superscript II]) in dopamine oxidation, related to Parkinsonism. The required prior knowledge is being familiar with the basis of UV-vis spectroscopy. Details of the activity, including procedure and…

Students in a typical instrumental analysis course may learn more than 30 analytical techniques. There are more than 150 components associated with the instrumentation that they learn. To help students organize this large amount of information, we classified these components into four categories: sources, samples, discriminators, and detectors. In…

The undergraduates in the major of Environmental Science and Environmental Engineering frequently ignored the importance of identifying pollution sources for water environment monitoring and knew little about the techniques of identifying pollution sources. Thus, a laboratory experiment which focused on pollution sources identification in a water…

Benchtop NMR spectrometers are now becoming more widely employed in university teaching laboratories. These low-field instruments are increasingly used in reaction monitoring and product purity applications. NMR spectra obtained using these spectrometers (40-80 MHz) tend to suffer from significant overlap of signals when compared to those obtained…

We report a research-enhanced undergraduate laboratory practical in which students synthesize and characterize color-controllable, stable silver nanoparticles for use in a simple catalytic reaction analyzed by UV-vis spectroscopy. The practical has been prepared for students using electronic laboratory notebooks, enables collaborative data…