Although ionic liquids have been investigated as solvents for many applications and are starting to be used in industrial processes, only a few lab experiments are available to introduce students to these materials. Ionic liquids have been discussed in the context of green chemistry, but few investigations have actually assessed the degree of…

We have developed a two-week guided-inquiry laboratory in which first-semester general chemistry students investigate a suspected arson using gas chromatography--mass spectrometry and paper chromatography. In the process of evaluating evidence from the crime scene, students develop and test hypotheses and learn the fundamentals of chromatography,…

Assigning a popular nonfiction book as a supplemental text in organic chemistry can help students learn valuable skills. An analysis of student feedback on assignments related to a nonfiction book in two different organic courses revealed that students applied the information from the book, improved their communication skills, and were more…

The jigsaw technique has been used in a fourth-year biochemistry course to increase problem-solving abilities of the students. The jigsaw method is a cooperative-learning technique that involves a group structure. Students start with a "home" group. That group is responsible for learning an assigned portion of a task. Then the instructor separates…

A novel experiment is described in which solvated electrons in liquid ammonia reduce a benzyl alcohol carbon without affecting the aromatic ring. The reductive activity of solvated electrons can be partially or completely quenched through the addition of electron scavengers to the reaction mixture. The effectiveness of these scavengers was found…

Diagrams and figures play a central role in science and science education. Research has indicated that, when presented and used properly in a classroom setting, these external representations can contribute to students' understanding of scientific concepts; however, it is apparent that students do not always use, understand, interpret, or value…

This case study's primary objective is to describe the implementation of the electronic response system (clickers) in a small (N = 25) second-year physics course at a large public university and to draw attention of the science faculty who teach upper-level science courses to the potential benefits of this pedagogy. This pilot study discusses the…

This study presents and interprets some conceptual difficulties junior-level physics students experience with Ampere's law. We present both quantitative data, based on students' written responses to conceptual questions, and qualitative data, based on interviews of students solving Ampere's law problems. We find that some students struggle to…

A hetero-Diels-Alder reaction that proceeds rapidly and only requires a simple filtration to purify the product is presented. The dienophile, 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD), is prepared by the heterogeneous oxidation of 4-phenylurazole by the bromenium ion, Br[superscript +], generated in situ by the oxidation of potassium bromide by…

Lasers have transformed chemistry and the everyday world. Therefore, it is not surprising that undergraduate chemistry students are frequently exposed to fairly advanced laser techniques. The usual topics studied with lasers are molecular spectroscopy and chemical kinetics. Static and dynamic fluorescence experiments seem to be particularly…

Extending the usefulness of the instruments we have has never been more important. The current economic crisis has prompted all of us to re-examine how money is spent and to try to minimize our expenditures because of future uncertainties. We have been able to breathe new life into an aging 60 MHz NMR spectrometer used by hundreds of…

The four-week student project described in this article is an extension of protein thermal denaturation experiments to include effects of added cosolutes ethylene glycol, glycine betaine, and urea on the unfolding of lysozyme. The transition temperatures and van't Hoff enthalpies for unfolding are evaluated for six concentrations of each cosolute,…

One-component phase diagrams are good approximations to predict pressure-temperature ("P-T") behavior of a substance in the presence of air, provided air pressure is not much higher than the vapor pressure. However, at any air pressure, and from the conceptual point of view, the use of a traditional "P-T" phase diagram is not strictly correct. In…

In this article I support and extend the ideas presented by J. Brent Friesen in his article "Saying What You Mean; Teaching Mechanisms in Organic Chemistry" ("JCE" November, 2008). I emphasize "telling the truth" about proton transfers. The truth is that in aqueous acid most reactions are subject to "specific" acid catalysis: the only kinetically…

Students in the second-semester organic chemistry laboratory perform a Wittig reaction between butylidenetriphenylphosphorane (an ylide) and benzaldehyde and determine the relative percentages of the cis and trans isomers of the 1-phenyl-1-pentene product. Because of the highly reactive nature of this unstabilized ylide, students are introduced to…