Significant figures in a measurement are all the digits known plus one more digit that is uncertain or estimated. The problem addressed by this study is inconsistencies in the instruction of significant figures in high school chemistry. This study examined teacher experience as related to the teaching of significant figures. The individuals…

This paper describes a data set of IR, MS, H-1 NMR, C-13 NMR, DEPT, and 2D NMR spectra designed for undergraduate teaching. The data files are provided as MestReNova documents containing all the available spectra for each of the 251 different compounds in the data set. The spectral data in these files can be processed, manipulated, copied, and…

The use of a multicompartment electrochemical cell for the potentiometric determination of solubility product constants of aqueous I[superscript -], Br[superscript -], SCN[superscript -], and Cl[superscript -] salts of silver is presented. An electrochemical cell presented in this study contained multiple half-cells made of disposable drinking…

The implementation of a laboratory exercise in an undergraduate chemistry course, where students perform a comparison of three different synthetic methods toward [Cu(Cl)(IPr)]-complexes (IPr = N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene), is described. The students are introduced to the continuous improvement of reactions in terms of green…

Within the past decade, escape rooms have aroused great social and educational interest. Their potential for intra- and extracurricular learning ranges from the promotion of methodical and communicative competencies to problem-solving and teamwork strategies. As a nonformal learning environment, the youth leisure sector is suitable for the…

An exciting recent development in chemistry has been the ability to control nanoparticle crystal morphology or shape. Nanoparticles of different shapes present different crystal surfaces (or facets) with respect to the surrounding environment. Synthetic control over nanoparticle morphology has enabled the study of the influence of surface facets…

The learners' conceptual understanding has become one of the leading research areas conducted by educational researchers. Both students and current educators should actively work to improve their understanding of alternative conceptions and deepen their conceptual knowledge. One of the essential concepts in chemistry learning is colligative…

At-home chemistry experiments are increasingly important to enable high-quality online and hybrid instruction. These class modalities provide significant challenges and also dramatically expand the accessibility of education to those who work or care for family during traditional school hours or have significant commutes to campus. This work…

A Spreadsheet Excel application for chromatographic peak characterization is described in this article. Data are exported from HPLC specific program to an Excel file with macros to perform basic calculations as retention time, height, and area of the peaks. From these values, peak resolution, asymmetry, or theoretical plates are calculated and…

A multistep assembly of gold nanoparticle self-assembled monolayers (SAMs) on glass surfaces is proposed, as a third-year undergraduate experiment. The process includes self-assembly (SA) and electrostatic self-assembly (ESA) methods, which are central approaches in modern surface and materials engineering. The products are analyzed using…

Gamification of learning in chemistry education is a growing field. Chemistry themed escape room activities, incorporating course learning objectives into puzzle solution, have become a popular tool allowing for students to apply course knowledge in novel settings. Escape room activities, like their public counterparts, provide subtle guidance to…

Reactions between metal carbonates from d[superscript 5] to d[superscript 10] systems and glutamic acid are used to obtain molecular metal complexes and metal-organic frameworks (MOFs). When the ligand is an amino acid, these MOFs belong to the BioMOF class (metal-organic frameworks for biological and medical applications). The metal carbonates of…

A laboratory experiment in which [superscript 1]H NMR and UV-vis spectroscopies are applied to probe the temperature dependence of a monomer-dimer equilibrium involving a cyclopentadienone derivative is described and discussed. Details of the data analysis for extraction of equilibrium constants from the raw experimental data from both techniques…

A convenient approach to obtain Lewis structures for compounds of the type YX[subscript n] involves first constructing a trial structure that satisfies the valence of the outer atoms (e.g.,1 bond for fluorine, 2 bonds for oxygen, and 3 bonds for nitrogen)and placing the molecular charge (if any) on the central atom. The second step involves…

Despite tremendous efforts by instructors and textbook authors, students find it difficult to develop useful chemical intuitions about structures and key properties of the important d-block organometallic species that have a d[superscript 6], d[superscript 8], or d[superscript 10] d-electron count. A full molecular orbital analysis is not always…