Instructive, inexpensive, and environmentally friendly laboratory syntheses of two highly luminescent copper(I) complexes CuI(PPh[subcript 3])[subscript 2](py[superscript R]) (py[superscript R] = pyridine, 4-cyanopyridine) are described for second-year/upper-division undergraduate inorganic chemistry students. Both complexes exhibit bright…

For the past century, humans have been increasingly dependent on plastics, but have not developed adequate disposal practices. In this lab, students are asked whether burning plastic for energy seems like a reasonable disposal technique. To answer the chemical aspects of this question, students use bomb calorimetry to quantify the combustion…

Biocompatible and biodegradable block copolymers composed of poly(ethylene glycol) (PEG) and aliphatic polyester are a class of promising biomaterials. Herein, a teaching experiment was designed to furnish undergraduates with a reliable method to synthesize an amphiphilic poly([epsilon]-caprolactone)-PEG-poly([epsilon]-caprolactone) (PCL-PEG-PCL)…

A low-cost multispectral imager was built using a multiwavelength LED PCB (light-emitting diode printed circuit board), 3D printed housing, and a monochrome camera, and it was controlled via National Instruments LabVIEW software coupled with some simple electronics. Multivariate data analysis was performed using freely available software packages.…

A series of hands-on experiments including the synthesis and application of flexible, conductive silver-nanopaste were designed to gain knowledge of conductive soft nanomaterial and the synthesis and the application of silver nanopaste (Ag nanopaste). The aim of this laboratory experiment is to provide undergraduate/graduate students an…

Organic chemistry is a required course sequence for many STEM students. However, research indicates that organic chemistry reaction mechanisms are especially challenging for students due to a mixture of underlying conceptual difficulties, the process-oriented thinking inherent to the discipline, and the representations commonly used to depict…

In the past decade, C-H functionalization has been a very active topic of research in both academia and industry. When a H atom is replaced by an aryl (or heteroaryl) group, the transformation is termed "direct arylation". This approach to the formation of key (hetero)aryl-(hetero)aryl bonds is complementary to traditional methods, such…

Undergraduate students in an environmental chemistry laboratory course were taught QuEChERS (quick, easy, cheap, effective, rugged, and safe), a sample preparation procedure that is commonly used in pesticide laboratories involving an acetonitrile salt-out extraction of fresh produce samples followed by solid-phase dispersive cleanup using a…

This article provides two additional mnemonics that can serve to help undergraduate students recall how to apply the rules of writing net ionic equations. These mnemonics were incorporated into dozens of lecture and laboratory class content, which includes hundreds of undergraduate (health professions and physical science major) students. As a…

The concept of a sinusoidal wave traveling along a string is included in all secondary education physics books and as a result is being taught in undergraduate lectures around the globe. The didactic approach that follows is advantageous since it provides in a simplified way (through basic mathematical tools) a description of a disturbance that…

Several studies have found active learning to enhance students' motivation and attitudes. Yet, faculty indicate that students resist active learning and censure them on evaluations after incorporating active learning into their instruction, resulting in an apparent paradox. We argue that the disparity in findings across previous studies is the…

We present the use of an oxygen tolerant controlled radical polymerization (photoinduced electron/energy transfer-reversible addition fragmentation chain transfer polymerization, PET-RAFT) as a simple method for preparing controlled radical polymers in an undergraduate laboratory. Unlike conventional techniques, PET-RAFT polymerizations require no…

Exciting developments in the field of Green Chemistry spur the continuous innovation of experiments in the teaching laboratory. Beyond learning practical techniques, students can critically assess experiments using relevant metrics to propose further improvements and identify the most important interconnected impacts of these alternative products…

Dendrite growth affects material systems across applications as diverse as lithium batteries, organic light emitting diodes, turbine blades, and biological sensors. Their unique crystal structure and ability to physically see growth make for a unique undergraduate laboratory experience. This experiment uses dendrite growth to explore the physical…

Recently, researchers have paid extensive attention to colorimetric/fluorimetric probe development and its applications in biological and industrial samples. The actual development of such probe molecules, however, often requires an iterative process to achieve certain goals such as selectivity and sensitivity toward a target analyte. In spite of…