Dilute guarana´ ("Paullinia cupana") powder aqueous extract is a soft drink that contains three structurally related methylxanthines (MXs), caffeine (CF), theobromine (TB), and theophylline (TP); CF is present in a large excess. Literature data show that values of [lambda][subscript max] and [epsilon][subscript max] of these three MXs…

Despite extensive conceptualization of ions as hard spheres in most textbooks, solid-state structures are more accurately modeled as overlapping soft spheres that better reflect the size of the ions. The corresponding soft-sphere ionic radii of alkali and halide ions can be empirically established from the partial molar volume of the ions in…

We developed a remote lab experience where freshmen grew and analyzed the activity of sourdough starters as a means of engaging with chemical engineering concepts. This six-week hands-on activity was targeted due to its low-cost, non-hazardous materials, and ability to be conducted safely in a non-laboratory setting. By designing the lab to be…

In this article, we describe a fully computational laboratory exercise that results in an increase of students' understanding of what quantum chemical geometry optimization calculations are doing to find minimum energy structures. This laboratory exercise was conducted several times over multiple years at a small private undergraduate institution,…

Quantum dots are colloidal semiconductor nanocrystals that display size-dependent electronic and optical properties. These materials are a visual demonstration of a quantum-mechanical effect. Here we present a laboratory exercise for undergraduate/Bachelor students as an introduction to colloidal nanocrystals and quantum dots. The students…

In this paper, we present a concise and technique-heavy route to the synthesis of dimedone for a second-year organic chemistry curriculum. Our preparation of dimedone guides students through a Michael addition followed by a Dieckmann cyclization, basic ester hydrolysis, and thermal decarboxylation, while allowing time for mechanistic discussion…

Metabolic Control Analysis (MCA) is a systems biology approach that measures the control of a metabolic step on the overall flux of a metabolic pathway. In undergraduate courses in biochemistry, learning of MCA can be encouraged by experimental activities demonstrating practical applications of the MCA theory. In this work, we present a laboratory…

Calorimetry is a central concept in the first semester general chemistry curriculum, and constant pressure (coffee-cup) calorimetry is a common experiment in the laboratory. However, constant volume (bomb) calorimetry is traditionally reserved for the physical chemistry laboratory. This article describes the advantages of incorporating bomb…

Undergraduate-level laboratory experiments that integrate multidisciplinary chemistry concepts into a single activity are very appealing and thought-provoking for chemistry students. Here, we use the oscillating chemical reaction to introduce students to the analytical detection concept. The Belousov-Zhabotinsky reaction is employed as a simple…

The field of DNA nanotechnology has grown rapidly in the past decade and has expanded to multiple laboratories. While lectures in DNA nanotechnology have been introduced in some institutions, laboratory components at the undergraduate level are still lacking. Undergraduate students predominantly learn about DNA nanotechnology through their…

Ultrafast laser pump-probe spectroscopy is an important and growing field of physical chemistry that allows the measurement of chemical dynamics on their natural time scales, but undergraduate laboratory courses lack examples of such spectroscopy and the interpretation of the dynamics that occur. Here we develop and implement an ultrafast…

Metal-air battery technology is a promising new energy storage solution in the green energy economy but also an excellent tool to educate students on the working principles of batteries. A simple yet powerful construction of a metal-air battery is shown, which consists of a plastic mint box, a cathode, an anode, and an electrolyte. Furthermore,…

This paper describes a case study of an online physics laboratory course implemented for 254 engineering students at Walailak University in Thailand in response to the COVID-19 pandemic. The laboratory sequence was designed based on the United Kingdom Professional Standards Framework and covered eight experiments on fundamental concepts of motion,…

A hydroponics experiment growing microgreens was piloted by seniors where trials were conducted over 9-day growth periods and designed to test 12 different growth conditions in triplicate, including varying nutrient supply, nutrient flow rate, and seed density. Plant growth was assessed through changes in daily mass, height, and final dry weight.…

To best prepare students for the real-world research environment, key skills, including experimental design, data analysis, communication of results, and critical thinking, should be key components of undergraduate science courses. Furthermore, the impact of the COVID-19 pandemic on in-person teaching has resulted in a need to develop courses that…