Einstein's relation between mass and energy is perhaps the most famous equation of Physics. Despite its simplicity, the meaning of E[subscript 0] = mc[superscript 2] is not easy to grasp. Furthermore, its traditional derivations rely either on the integral of "momentum," on properties of electromagnetic radiation, or even on the…

When the thermal expansion of water is discussed in school or university lessons, functional relationships are often inferred without considering measurement uncertainties. Moreover, in some learning materials, the goal of experimentation and the experimental setup do not match. This creates the wrong picture of scientific practice. In this…

Thermodynamic characterization of micelle formation from an ionic surfactant in aqueous solutions is a classic experiment in physical chemistry. The critical micelle concentration (CMC) and the degree of micelle ionization ([alpha)] can be directly obtained by conductimetry, then thermodynamic parameters ([delta]G[subscript m][superscript o],…

The free radical chlorination of an alkane experiment is often used in the undergraduate laboratory curriculum to introduce students to the free radical mechanism, substituent effects, intermediate stability, and the relative reactivity of radicals. In this experiment, students monochlorinate multiple alkanes and analyze the reaction mixture using…

Inductively coupled plasma optical emission spectroscopy (ICP-OES) is one of the most commonly used analytical techniques for the measurement of metals in environmental matrices. However, one of the drawbacks of ICP-OES is interference, viz., spectral and nonspectral (due to transport effects) interference. In this simple laboratory experiment,…

Keto-enol tautomerism is a special example of structural isomerism. In this experiment, 6-chlorofulvene is predominantly yielded during the chlorination reaction of 6'-hydroxyfulvene with POCl[subscript 3] in the presence of DMF. The high regioselectivity of this reaction is dominated by intramolecular hydrogen-bonding and steric hindrance,…

In this brief experiment, students create a superhydrophobic surface as an application of polar--nonpolar interactions and redox chemistry. Half of a zincgalvanized steel strip is coated in copper nanoparticles through electroless deposition. A layer of nonpolar octadecanethiol is added to half of that copper surface. Students classify the three…

Experimental electrochemistry offers unique opportunities for interactive instruction at all levels of education; however, widespread adoption in curricula is hindered by high costs associated with electrochemical instrumentation. Thus, the development of affordable instruments represents an essential step toward making electrochemistry accessible…

A laboratory activity is described for senior high school or first year undergraduate level students that illustrates key concepts linked to extractive metallurgy. This experiment demonstrates preferential binding of a methoxyphenolic oxime ligand to Cu[superscript 2+] in the presence of other transition metal ions in aqueous solution. The…

Works of art have value not only as entertainment and aesthetic expression -- they also externalize features of human cognition that would often otherwise remain hidden. A musical example from the 19th century is a striking case in point. In 1819, Austrian music publisher, editor, and composer Anton Diabelli invited fifty-one of Austria's most…

The American Chemical Society advocates a shift from rule-based to risk-based safety education for chemistry graduates, emphasizing meaningful student engagement in the risk assessment process for laboratory work. To implement this paradigm shift, we introduced RAMP (Recognize Hazards, Assess Risk, Minimize Risk, and Prevent Emergencies)-based…

Both lecture and laboratory courses of biochemistry are important professional courses for undergraduates with biology related majors. Course optimization and update is crucial but challenging, especially for the laboratory course. Although taught separately, here we showed a strategy to bridge the two courses and promote the improvement of both.…

CACAO (Chocolate Across the Curriculum and Outreach) is a vertical curriculum augmentation designed to help students across the ChE undergraduate program. The students use a chocolate-based food engineering lab to make connections between core chemical engineering topics using hands-on and project-based learning. Costs to create this component are…

A digital information explosion has transformed cities' residential and educational markets in ways that are still being uncovered. Although urban stratification scholars have increasingly scrutinized whether emerging digital platforms disrupt or reproduce longstanding segregation patterns, direct links between one theoretically important form of…

[This paper is part of the "Focused Collection on Instructional Labs: Improving Traditions and New Directions."] Recent studies provide evidence that social constructivist pedagogical methods such as active learning, interactive engagement, and inquiry-based learning, while pedagogically more effective, can enable inequities in the…