Metacognitive functions are important for both teachers and students to facilitate teaching and learning. The prefrontal cortex (PFC) plays a proven role in metacognition. As a pilot study, we evaluated the PFC activity of teachers and students using near-infrared spectroscopy devices to explore the neural mechanism of PFC underlying metacognitive…

Micellar catalysis has become an important aspect of the chemical industry's effort to "go green". However, this chemistry has yet to be fully explored in educational settings such as second-year organic chemistry laboratories. Reported herein is a discovery-based nucleophilic aromatic substitution experiment that introduces chemistry…

It is under debate whether the neural representation of numbers and letters might rely on distinct neural correlates, or on a mostly shared neural network. In the present study, a total of 47 children in fifth grade (Experiment 1) and sixth grade (Experiment 2) simply copied numbers and letters on a touch screen while brain activation changes were…

Inorganic phosphors are the main component of light emitting diodes which have caused the revolution in lighting industry as an energy-efficient and long-lasting replacement of traditional incandescent light bulbs and fluorescent tubes. They are also used in various consumer products and displays and can potentially find applications in…

The research presented in this dissertation looks at how students in general chemistry reason about atomic emission spectroscopy. Situated within the context of a transformed general chemistry curriculum called "Chemistry, Life, the Universe, and Everything" (CLUE), the goal of this study was to (1) characterize the various ways in which…

[superscript 31]P{[superscript 1]H} nuclear magnetic resonance spectroscopy is a particularly useful tool for studying the reactions of P-donor ligands such as phosphines and phosphites with transition metals and other Lewis bases because the reactions take place on the nonbonding pair of electrons on the phosphorus. In addition, [superscript 31]P…

In this paper, we report an experiment intended as a tool to introduce chemistry and materials science students to several chemical concepts through the determination of the best experimental conditions for the formation of calcium oxide (lime) from a source of high content of calcium carbonate (eggshells). Thermal gravimetric analysis (TGA),…

We report here a method that utilizes the vapor pressure of HCl(g) above a concentrated HCl(aq) solution as an extremely simple and safe method to produce small amounts of HCl vapor in an IR gas cell. This vapor pressure approach can also be used to produce DCl(g) by introducing a few drops of concentrated DCl(aq) into the gas cell.

Adsorption of methylene blue and malachite green was carried out using "Luffa cylindrica" sponges as adsorbing material. We provide a very illustrative exercise about the use of common natural materials requiring little preparation to solve environmental tasks in a routine laboratory situation such as using dyes. In addition, the…

An experiment involving a moisture-sensitive synthesis and spectroscopic characterization suitable for the advanced inorganic laboratory course is presented. The acid-base complex ammonia borane (AB) is synthesized from the heterogeneous reaction between sodium borohydride and finely ground ammonium sulfate in tetrahydrofuran solvent. AB is…

Reported herein is a multidisciplinary laboratory experiment for advanced undergraduate students that includes elements of material synthesis, in the synthesis of cyclodextrin-containing metal-organic frameworks (CD-MOFs), and environmental chemistry, in the use of these MOFs for pollutant removal. This multiday laboratory experiment starts with…

Harmful plastic debris found on beaches and in the oceans are not limited to drinking straws or bags. There are several synthetic organic polymers that can be used to make different kinds of plastic materials and have resulted in billions of tons of waste that can reach the aquatic biome and are harmful to freshwater and marine communities as well…

The Environmental education navigates students towards environmentally friendly life style and securing a quality of life. The implementation of cross-section topics, including the Environmental education, into science classes, is possible through a variety of techniques. One of the least used methods is a real school experiment. The following…

Rovibrational spectroscopy is a fundamental component of most physical chemistry curricula. This article describes an adaption of the rovibrational spectroscopy of carbon dioxide experiment that can be used as a stand-alone experiment or in conjunction with a traditional hydrogen chloride experiment. The case is made that the laboratory…

Strategies for teaching NMR spectral interpretation in the undergraduate organic chemistry curriculum are often faculty-centered and can lead to student reliance on rote memorization and "guess and check" methods rather than critical-thinking skills for structure determination. This article describes a student-focused methodology for the…