Describes a simple and reliable test method used to investigate the corrosion-inhibiting effects of various chelating agents on aluminum pigments in aqueous alkaline media. The experiments that are presented require no complicated or expensive electronic equipment. (DDR)

Presents investigations of leaf surface wetness that provide ideal opportunities for students to explore the relationships between leaf form and function, to study surface conditions of leaves and plant physiology, and to make predictions about plant adaptation in different environments. Describes simple procedures for exploring questions related…

Presents 6 short experiments with liquid nitrogen that 12- and 13-year-old students can safely perform under close supervision. Helps the students in learning a number of basic chemical principles while spurring their curiosity and showing them how much fun chemistry can be. (JRH)

Tells the story of an experiment conducted by Galileo and proves that a light pebble and a heavy rock travel with equal speed when dropped from the same distance and touch the ground at the same time. Indicates the importance of open-mindedness and tolerance. First published in 1939. (YDS)

Epoxide chemistry is widely used in organic synthesis and regularly discussed in organic chemistry textbooks. An experiment to generate dimethyldioxirane in situ from acetone using Oxone is explained.

The experiment describes the regioselective synthesis of a stereodefined push-pull alkene from inexpensive chemicals. Important concepts in organic chemistry, such as resonance theory and role of solvent polarity on formation of intra- and intermolecular hydrogen bonds, which affect the configuration of the double bond in predictable way are…

The increase in NMR relaxation rates as a result of dissolved paramagnetic species on the sample of superoxygenated drinking water is demonstrated. It is concluded that oxygen content in NMR samples is an important issue and can give rise to various problems in the interpretation of both spectroscopic and NMR imaging or relaxation experiments.

An experiment on kinetics of deactivation of carbonic anhydrase by removal of zinc is demonstrated. Carbonic anhydrase, the enzyme that catalyzes the interconversion of carbon dioxide and bicarbonate, requires on Zn(II) ion in its active site, and removal of the zinc cofactor by complexion to another ligand leaves the apoenzyme, which is totally…

A survey of progress made over the past ~30 years (1970 - 2004) to improve the reliability of surface analyses by XPS is presented. The basic principles of XPS are very simple yet there is considerable complexity in designing experiments, interpreting data, and analyzing the results for the many different modes of operation and many different…

A mixture of potassium hydroxide and alpha-naphthaldehyde (1) are heated under solvent-free conditions to produce 1-naphthoic acid (2) and 1-naphthalenemethanol (3). The experiment offers several advantages over many existing exercises including the ease of reaction workup, shorter reaction time, relative environmental friendliness of the…

An experiment that highlights the role electrochemistry plays in the fabrication of nanoscale structures is presented. The movement and alignment of the nickel nanowires were observed, when manipulated using magnetic fields through the lens of an optical microscope using common magnets to alter the applied magnetic field.

An experiment is presented that introduces students to nanotechnology through the preparation of nanoparticles and their visualization using transmission electron microscopy (TEM). The experiment familiarizes the students with nonaqueous solvents, biphasic reactions, phase-transfer agents, ligands to stabilize growing nanoparticles, and bidentate…

The technique for producing quantum-sized zinc oxide (ZnO) particles is much safer than a technique that used hydrogen sulfide gas to produce cadmium sulfide and zinc sulfide nanoparticles. A further advantage of this method is the ability to sample the solution over time and hence determine the growth kinetics.

A facile synthesis of two gold(I) complexes with 1,2-benzenedithiolate ligand and two different bidentate phosphines are described. A detailed sequence of NMR experiments is suggested to determine the structure of the compounds.

A laboratory course called cytochrome c that focuses on the theme of biochemical research is presented. The students follow this course by incorporating team-investigation and self-directed experimentation that provides them an opportunity to experience the excitement of research.