A critical factor for the increased nucleophilicity of the pyridine nitrogen in 4-(dimethylamino)pyridine (DMAP) is electron donation via resonance from the amino group into the aromatic ring that increases electron density on the pyridine nitrogen. To explore how important this resonance effect is, 4-(dimethylaminomethyl)pyridine (DMAMP) was…

We describe the projects "Eratosthenes 2009" and "Eratosthenes 2010 America," carried out during the International Year of Astronomy (2009) in Argentina and with almost all the countries in North and South America during 2010. More than 15000 students at more than 200 schools each year determined the radius of the Earth using…

Plastic water bottles are convenient containers for demonstrations of gas properties illustrating Boyle's law, Charles's law, and Avogadro's law. The contents of iron-based disposable hand warmer packets can be used to remove oxygen gas from the air within an unfilled plastic water bottle.

A student activity that focuses on the isolation of glucoraphanin from broccoli using preparative high-performance liquid chromatography (HPLC) is presented here. Glucoraphanin is a glucosinolate, whose byproducts are known to possess anticancer properties. It is present naturally at high levels in broccoli and other "Brassica" vegetables. This…

Schlieren imaging is a method for visualizing differences in refractive index as caused by pressure or temperature non-uniformities within a medium, or as caused by the mixing of two fluids. It is an inexpensive yet powerful and straightforward tool for sensitive and high-resolution visualization of otherwise invisible phenomena. In this article,…

Paramagnetic and diamagnetic materials are now generally known as the "Cinderella" materials of the magnetic world. However, susceptibility measurements made on these materials in the past have revealed many details about the molecular bonding and the atomic structure of the so-called "transition" elements. Indeed, the magnetic moment of neodymium…

How effective is training frogs to jump? This is perhaps the most frequent question in biology that is subjected to statistical analysis: does a treatment make a difference? One can examine whether there is indeed a training effect, by first assuming the opposite. That is, the authors assume that training has no effect on the mean distance jumped.…

The behavior of smoke rings, tornados, and quantized vortex rings in superfluid helium has many features in common. These features can be described by the same mathematics we use when introducing Ampere's law in an introductory physics course. We discuss these common features. (Contains 7 figures.)

A simple and direct method for measuring the absorption of carbon dioxide by two different substances is described. Lithium hydroxide has been used for decades to remove the gas from enclosed living spaces, such as spacecraft and submarines. The ratio of the mass of carbon dioxide absorbed to the mass of lithium hydroxide used obtained from this…

A titration curve with multiple inflection points results when a mixture of two or more reducing agents with sufficiently different reduction potentials are titrated. In this experiment iron(II) complexes are combined into a mixture of reducing agents and are oxidized to the corresponding iron(III) complexes. As all of the complexes involve the…

This study aims to examine the impacts of the inquiry learning strategies employed in a "Plastic Education Project" on primary students' knowledge, beliefs and intended behaviour in Hong Kong. Student questionnaires and a test on plastic types were adopted for data collection. Results reveal that the inquiry learning strategies…

The classroom, with its complex social structure and kaleidoscope of cognitive and phycho-sociological variables, has not often been the object of serious research. Content area specialists have concentrated on the sequential organization of materials and have left the direct applications of these materials, either to the intuitive strategies of…

Currently, there are a number of educational applications that allow students to reinforce theoretical or numerical concepts through an interactive way. More precisely, in the field of the analytical chemistry, MATLAB has been widely used to write easy-to-implement code, facilitating complex performances and/or tedious calculations. The main…

We describe a laboratory experiment that employs the Nanoceria Reducing Antioxidant Capacity (or NanoCerac) Assay to introduce students to portable nanoparticle-based paper sensors for rapid analysis and field detection of polyphenol antioxidants. The experiment gives students a hands-on opportunity to utilize nanoparticle chemistry to develop…

Photochemical upconversion is a regenerative process that transforms lower-energy photons into higher-energy light through two sequential bimolecular reactions, triplet sensitization of an appropriate acceptor followed by singlet fluorescence producing triplet-triplet annihilation derived from two energized acceptors. This laboratory directly…