Reactions between metal carbonates from d[superscript 5] to d[superscript 10] systems and glutamic acid are used to obtain molecular metal complexes and metal-organic frameworks (MOFs). When the ligand is an amino acid, these MOFs belong to the BioMOF class (metal-organic frameworks for biological and medical applications). The metal carbonates of…

A laboratory experiment in which [superscript 1]H NMR and UV-vis spectroscopies are applied to probe the temperature dependence of a monomer-dimer equilibrium involving a cyclopentadienone derivative is described and discussed. Details of the data analysis for extraction of equilibrium constants from the raw experimental data from both techniques…

A convenient approach to obtain Lewis structures for compounds of the type YX[subscript n] involves first constructing a trial structure that satisfies the valence of the outer atoms (e.g.,1 bond for fluorine, 2 bonds for oxygen, and 3 bonds for nitrogen)and placing the molecular charge (if any) on the central atom. The second step involves…

Despite tremendous efforts by instructors and textbook authors, students find it difficult to develop useful chemical intuitions about structures and key properties of the important d-block organometallic species that have a d[superscript 6], d[superscript 8], or d[superscript 10] d-electron count. A full molecular orbital analysis is not always…

We developed a fluorescence microscopy lesson geared towards high school students. Our goals included demonstrating how fluorescence microscopy works and illustrating the localisation of key cellular structures/organelles in the model organism, budding yeast. A trained student teacher/researcher on our team took the microscopy images and…

The equilibrium potential of an ion species is a crucial concept for medical students, as it is a prerequisite to fully understanding the pathophysiology of K+ imbalances (hyperkalemia and hypokalemia) in clinical practice. However, it remains a challenging concept because current medical physiology textbooks are too simplistic and overlook…

This research paper aims to propose a novel didactic sequence inspired by an historical/epistemological study of the evolution of spectroscopy and in particular of colorimetry. The working principles of the historical color comparators and the visual color matching method, first proposed by Duboscq, stimulated us in the development of a five-step…

This study aims to determine the need for multitiered diagnostic instruments to identify misconceptions and their causes, as well as multi-representational profiles in chemistry lessons starting from grade 10 in the initial to the final material for grade 12. The data analysis technique used in this research is descriptive, namely descriptive…

In this study, teaching materials related to the history of science (HOS) related to the Boyle-Hobbes debate were developed through the analytical lens of framing theory. Further, this study developed the teaching materials for learning the social-institutional aspects of the reconceptualized family resemblance approach (FRA) to the nature of…

A chemistry laboratory experiment is described to introduce undergraduate college students to membrane separation technology. This experiment combines a simple nanowire membrane fabrication and visually indicated molecule separation. The membrane is produced via coprecipitation synthesis followed by a filtration assembly process, which can be…

The measurement of glucose through electrochemical methods is a great example to illustrate the practical application of electrochemistry. Although many students enrolled in chemistry classes are familiar with the glucose meter, only a few have delved into the underlying principles governing its operation. This experiment aims to address this gap…

Students' lack of understanding and ability to conceptualize chemistry material in real life requires an effort to integrate chemistry learning with cultural values or local wisdom. One such effort is the process of making eco-prints. This research aims to uncover the ethnoscience aspects (chemistry) involved in producing and selecting eco-print…

As a widely applied theory that has found success across many fields, density functional theory (DFT) is largely taught. Typically, the most effective way to convey DFT concepts is through illustrative examples that are currently lacking in available resources. In this work, we demonstrate total energy calculations for H[subscript 2] using…

The electrolysis of water to produce hydrogen is a critical step in many green chemistry processes. The key to the efficiency of water electrolysis is the synthesis of an appropriate electrocatalyst. Three-dimensional (3D) printing is an increasingly important part of many industrial processes. In this study, we propose an efficient laboratory…

A one-pot regio- and stereoselective synthesis of a dipyrromethane and a bis(indolyl)methane based on two consecutive reactions of nitrosoalkenes with pyrrole or indole, respectively, is described as an experiment to be carried out by upper-division undergraduate students in a laboratory classroom. Importantly, the ability of electrophilic…