By adapting a well-established expository style practical on the topic of chemoselectivity, we present our successful approach to introducing elements of guided inquiry and decision-making to novice undergraduate chemists. Using nitroacetophenone as the polyfunctional substrate, students investigate the effect of using two different classes of…

As an introduction to quadrupolar effects in NMR spectroscopy, students use low field ([superscript 1]H, 60 MHz), benchtop [superscript 13]C NMR spectroscopy to contrast the spin-spin coupling behavior of [superscript 13]C to the dipolar [superscript 1]H and quadrupolar [superscript 2]D in familiar solvents C(H/D)Cl[subscript 3], C(H/D)[subscript…

General spectroscopy is known to be difficult for novice students due to its complex and abstract nature. In this study we used a first-year chemistry Mini Spec laboratory activity to uncover language barriers to student learning in spectroscopy. Analysis revealed that language barriers generated conceptual difficulties for English as Second…

The education science (or pedagogy based on scientific principles) of the learning of spectroscopy analysis in terms of critical thinking was examined in a community college setting with high school outreach and senor college transfer students enrolling in courses and/or projects. The most important discovery of science in the 20th Century was the…

Newborns are able to neurally discriminate between speech and nonspeech right after birth. To date it remains unknown whether this early speech discrimination and the underlying neural language network is associated with later language development. Preterm-born children are an interesting cohort to investigate this relationship, as previous…

Frontal asymmetry (FA), the difference in brain activity between the left versus right frontal areas, is thought to reflect approach versus avoidance motivation. This study (2012-2021) used functional near-infrared spectroscopy to investigate if infant (M[subscript age] = 7.63 months; N = 90; n = 48 male; n = 75 White) FA in the dorsolateral…

Here we showcase an undergraduate teaching laboratory in which students synthesize and characterize colloidal nanoparticles of organic semiconductors and assess their suitability for applications in printed electronics such as solar cells and bioelectronics. Scanning electron microscopy, UV-visible spectroscopy, and photoluminescence spectroscopy…

The pharmacologically active lignans sesamin and sesamolin are minor components of sesame oil and ingredients in OTC dietary supplement capsules. We report an introductory undergraduate organic laboratory experiment combining natural product isolation and spectral analysis in which students isolate a mixture of sesamin and sesamolin by either (1)…

The carbonyl group of an aldehyde or ketone reacts with different types of nucleophiles through a nucleophilic addition reaction. When the nucleophile is water, the product obtained is a "gem"-diol or geminal diol. This functionalization is unstable and quickly reverts to the parent carbonyl group. The chemistry of "gem"-diols…

A laboratory experiment was designed to provide students with an introduction to byproduct valorization by producing an analogue of biodiesel (fatty acid ethyl esters, FAEE) via lipid extraction and subsequent transesterification from spent coffee grounds (SCG). Valorization is the process of upgrading underutilized or discarded wastes or…

This laboratory experiment consists of the synthesis of two series of alkaline-earth titanates (calcium-strontium and strontium-barium)to corroborate Vegard's law by obtaining their X-ray diffraction patterns and plotting the lattice parameter versus mole fraction of both cations. This experiment allows students to understand the key concepts in…

NMR spectroscopy is a powerful spectroscopic tool that not only allows the determination of structures after synthesis, as usually explained to students of Organic Chemistry, but also is useful in many other fields such as medicine imaging, real-time industrial processes, material sciences, or metabolomics. In this experiment, students performed a…

The integration of physics, music, and mathematics has long been used to increase students' interest and motivation in these subjects. For example, previous articles in this journal have shown how to teach physical concepts in a musical context, use a smartphone to check the resonant frequencies of whistles, use a smartphone to examine the spectra…

A bilingual environment is associated with changes in the brain's structure and function. Some suggest that bilingualism also improves higher-cognitive functions in infants as young as 6-months, yet whether this effect is associated with changes in the infant brain remains unknown. In the present study, we measured brain activity using functional…

Increased focus on resting-state functional connectivity (rsFC) and the use and accessibility of functional near-infrared spectroscopy (fNIRS) have advanced knowledge on the interconnected nature of neural substrates underlying executive function (EF) development in adults and clinical populations. Less is known about the relationship between rsFC…